摘要
A new chiral copper borophosphate, LiCu2[BP2O 8(OH)2] (1), was crystallized from achiral inorganic raw materials in boric acid flux reaction. The structure features a 9-ring channel enclosed by triple right-handed helices. The bulk sample exhibits optical activity confirmed by circular dichroism (CD) spectra, indicating an interesting spontaneous resolution phenomenon.
源语言 | 英语 |
---|---|
页(从-至) | 6298-6301 |
页数 | 4 |
期刊 | Dalton Transactions |
卷 | 42 |
期 | 18 |
DOI | |
出版状态 | 已出版 - 2013 |
已对外发布 | 是 |
指纹
探究 'LiCu2[BP2O8(OH)2]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization' 的科研主题。它们共同构成独一无二的指纹。引用此
Yang, M., Li, X., Yu, J., Zhu, J., Liu, X., Chen, G., & Yan, Y. (2013). LiCu2[BP2O8(OH)2]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization. Dalton Transactions, 42(18), 6298-6301. https://doi.org/10.1039/c3dt50591j