LiCu2[BP2O8(OH)2]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization

Miao Yang*, Xinjie Li, Jihong Yu, Jingran Zhu, Xiaoxia Liu, Genfu Chen, Yan Yan

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

17 引用 (Scopus)

摘要

A new chiral copper borophosphate, LiCu2[BP2O 8(OH)2] (1), was crystallized from achiral inorganic raw materials in boric acid flux reaction. The structure features a 9-ring channel enclosed by triple right-handed helices. The bulk sample exhibits optical activity confirmed by circular dichroism (CD) spectra, indicating an interesting spontaneous resolution phenomenon.

源语言英语
页(从-至)6298-6301
页数4
期刊Dalton Transactions
42
18
DOI
出版状态已出版 - 2013
已对外发布

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Yang, M., Li, X., Yu, J., Zhu, J., Liu, X., Chen, G., & Yan, Y. (2013). LiCu2[BP2O8(OH)2]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization. Dalton Transactions, 42(18), 6298-6301. https://doi.org/10.1039/c3dt50591j