Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

Wei Hui Fang; Guo Yu Yang

doi:10.1007/s10876-014-0717-1

Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

Wei Hui Fang, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

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摘要

A novel hydroxo-lanthanide cluster organic framework, Sm₃L₈(μ₃-OH)(H₂O)·H₂O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm₆ cluster unit is composed of inorganic tetranuclear hydroxo [Sm₄(OH)₂]¹⁰⁺ (Sm₄) cluster and dimeric [Sm₂(COO)₄]²⁺ (Sm₂) core. The Sm₆ cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.

源语言	英语
页（从-至）	1401-1411
页数	11
期刊	Journal of Cluster Science
卷	25
期	5
DOI	https://doi.org/10.1007/s10876-014-0717-1
出版状态	已出版 - 1 9月 2014
已对外发布	是

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@article{b479403777704b8abfcaea457bbde396,

title = "Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units",

abstract = "A novel hydroxo-lanthanide cluster organic framework, Sm3L8(μ3-OH)(H2O)·H2O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm6 cluster unit is composed of inorganic tetranuclear hydroxo [Sm4(OH)2]10+ (Sm4) cluster and dimeric [Sm2(COO)4]2+ (Sm2) core. The Sm6 cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.",

keywords = "Hexanuclear, Hydrothermal synthesis, Lanthanide cluster, Sql",

author = "Fang, {Wei Hui} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2014, Springer Science+Business Media New York.",

year = "2014",

month = sep,

day = "1",

doi = "10.1007/s10876-014-0717-1",

language = "English",

volume = "25",

pages = "1401--1411",

journal = "Journal of Cluster Science",

issn = "1040-7278",

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number = "5",

}

TY - JOUR

T1 - Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2014/9/1

Y1 - 2014/9/1

N2 - A novel hydroxo-lanthanide cluster organic framework, Sm3L8(μ3-OH)(H2O)·H2O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm6 cluster unit is composed of inorganic tetranuclear hydroxo [Sm4(OH)2]10+ (Sm4) cluster and dimeric [Sm2(COO)4]2+ (Sm2) core. The Sm6 cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.

AB - A novel hydroxo-lanthanide cluster organic framework, Sm3L8(μ3-OH)(H2O)·H2O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm6 cluster unit is composed of inorganic tetranuclear hydroxo [Sm4(OH)2]10+ (Sm4) cluster and dimeric [Sm2(COO)4]2+ (Sm2) core. The Sm6 cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.

KW - Hexanuclear

KW - Hydrothermal synthesis

KW - Lanthanide cluster

KW - Sql

UR - http://www.scopus.com/inward/record.url?scp=84956829634&partnerID=8YFLogxK

U2 - 10.1007/s10876-014-0717-1

DO - 10.1007/s10876-014-0717-1

M3 - Article

AN - SCOPUS:84956829634

SN - 1040-7278

VL - 25

SP - 1401

EP - 1411

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 5

ER -

Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

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