Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n, possessing infinite Ln-O-Ln linkages

De Xin Hu; Pang kuan Chen; Feng Luo; Yun Xia Che; Ji Min Zheng

doi:10.1016/j.molstruc.2006.10.027

Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages

De Xin Hu, Pang kuan Chen, Feng Luo, Yun Xia Che, Ji Min Zheng^*

^*此作品的通讯作者

Nankai University

科研成果: 期刊稿件 › 文章 › 同行评审

14 引用（Scopus）

摘要

Two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n 1 and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n 2 (H₂isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monoclinic system with P2₁/c space group. The X-ray single-crystal structure analysis reveals that center metal ions Ln(III) are nine-coordinated and linked by μ₂-Ocoo^- groups to form the [Ln2-(μ₂-Ocoo^-)₂-Ln1]_n inorganic-organic chains and finally to furnish the supramolecular framework structures. The thermogravimetric analyses were carried out to examine the thermal stability of these two complexes. Magnetic studies on the polycrystalline sample shows the existence of strong antiferromagnetic couplings between the adjacent Dy³⁺ ions in compound 2.

源语言	英语
页（从-至）	179-184
页数	6
期刊	Journal of Molecular Structure
卷	837
期	1-3
DOI	https://doi.org/10.1016/j.molstruc.2006.10.027
出版状态	已出版 - 30 6月 2007
已对外发布	是

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10.1016/j.molstruc.2006.10.027

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Hu, D. X., Chen, P. K., Luo, F., Che, Y. X., & Zheng, J. M. (2007). Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages. Journal of Molecular Structure, 837(1-3), 179-184. https://doi.org/10.1016/j.molstruc.2006.10.027

@article{5a72bda9c1d8400080a807b3d1ad6d73,

title = "Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n, possessing infinite Ln-O-Ln linkages",

abstract = "Two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n 1 and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n 2 (H2isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monoclinic system with P21/c space group. The X-ray single-crystal structure analysis reveals that center metal ions Ln(III) are nine-coordinated and linked by μ2-Ocoo- groups to form the [Ln2-(μ2-Ocoo-)2-Ln1]n inorganic-organic chains and finally to furnish the supramolecular framework structures. The thermogravimetric analyses were carried out to examine the thermal stability of these two complexes. Magnetic studies on the polycrystalline sample shows the existence of strong antiferromagnetic couplings between the adjacent Dy3+ ions in compound 2.",

keywords = "Antiferromagnetic, Hydrothermal reaction, Isophthalate, Lanthanide, Ligand",

author = "Hu, {De Xin} and Chen, {Pang kuan} and Feng Luo and Che, {Yun Xia} and Zheng, {Ji Min}",

year = "2007",

month = jun,

day = "30",

doi = "10.1016/j.molstruc.2006.10.027",

language = "English",

volume = "837",

pages = "179--184",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

Hu, DX, Chen, PK, Luo, F, Che, YX & Zheng, JM 2007, 'Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages', Journal of Molecular Structure, 卷 837, 号码 1-3, 页码 179-184. https://doi.org/10.1016/j.molstruc.2006.10.027

Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages. / Hu, De Xin; Chen, Pang kuan; Luo, Feng 等.
在: Journal of Molecular Structure, 卷 837, 号码 1-3, 30.06.2007, 页码 179-184.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n, possessing infinite Ln-O-Ln linkages

AU - Hu, De Xin

AU - Chen, Pang kuan

AU - Luo, Feng

AU - Che, Yun Xia

AU - Zheng, Ji Min

PY - 2007/6/30

Y1 - 2007/6/30

N2 - Two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n 1 and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n 2 (H2isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monoclinic system with P21/c space group. The X-ray single-crystal structure analysis reveals that center metal ions Ln(III) are nine-coordinated and linked by μ2-Ocoo- groups to form the [Ln2-(μ2-Ocoo-)2-Ln1]n inorganic-organic chains and finally to furnish the supramolecular framework structures. The thermogravimetric analyses were carried out to examine the thermal stability of these two complexes. Magnetic studies on the polycrystalline sample shows the existence of strong antiferromagnetic couplings between the adjacent Dy3+ ions in compound 2.

AB - Two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n 1 and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n 2 (H2isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monoclinic system with P21/c space group. The X-ray single-crystal structure analysis reveals that center metal ions Ln(III) are nine-coordinated and linked by μ2-Ocoo- groups to form the [Ln2-(μ2-Ocoo-)2-Ln1]n inorganic-organic chains and finally to furnish the supramolecular framework structures. The thermogravimetric analyses were carried out to examine the thermal stability of these two complexes. Magnetic studies on the polycrystalline sample shows the existence of strong antiferromagnetic couplings between the adjacent Dy3+ ions in compound 2.

KW - Antiferromagnetic

KW - Hydrothermal reaction

KW - Isophthalate

KW - Lanthanide

KW - Ligand

UR - http://www.scopus.com/inward/record.url?scp=34247127830&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2006.10.027

DO - 10.1016/j.molstruc.2006.10.027

M3 - Article

AN - SCOPUS:34247127830

SN - 0022-2860

VL - 837

SP - 179

EP - 184

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n, possessing infinite Ln-O-Ln linkages

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Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages