TY - JOUR
T1 - Hydrothermal synthesis and characterization of a new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2]
AU - Wang, Mei
AU - Li, Ji Yang
AU - Li, Yi
AU - Song, Xiao Wei
AU - Yu, Ji Hong
AU - Xu, Ru Ren
PY - 2005/6
Y1 - 2005/6
N2 - A new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2] (compound I) was synthesized hydrothermally. It crystallizes in the monoclinic space group P21/c with a=1.10240(7) nm, b=0.69551(4) nm, c=0.92805(5) nm, β=111.027(3)°, Z=6, R1=0.0379, wR2=0.0792 (all data). Its structure contains [Al2(PO4)2 (H2O)2 F2]2- macroanonic sheets built up from PO3(=O) tetrahedra and AlO3F2(H2O) octahedra to form three-, four-, six-membered ring-net stacked sheets in an AAAA sequence along [100] direction. The sheets are held together by diprotonated piperazine cations decomposed from 1-methylpiperazine through extensive hydrogen bonds.
AB - A new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2] (compound I) was synthesized hydrothermally. It crystallizes in the monoclinic space group P21/c with a=1.10240(7) nm, b=0.69551(4) nm, c=0.92805(5) nm, β=111.027(3)°, Z=6, R1=0.0379, wR2=0.0792 (all data). Its structure contains [Al2(PO4)2 (H2O)2 F2]2- macroanonic sheets built up from PO3(=O) tetrahedra and AlO3F2(H2O) octahedra to form three-, four-, six-membered ring-net stacked sheets in an AAAA sequence along [100] direction. The sheets are held together by diprotonated piperazine cations decomposed from 1-methylpiperazine through extensive hydrogen bonds.
KW - Fluoroaluminophosphate
KW - Host-guest interaction
KW - Hydrothermal synthesis
KW - Layered structure
UR - http://www.scopus.com/inward/record.url?scp=21144438624&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:21144438624
SN - 0251-0790
VL - 26
SP - 1027
EP - 1029
JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
IS - 6
ER -