Hydrogen-bonded helices in the layered aluminophosphate (C 2H8N)2[Al2(HPO4)(PO 42]

Yu Song; Jihong Yu; Yi Li; Guanghua Li; Ruren Xu

doi:10.1002/anie.200353118

Hydrogen-bonded helices in the layered aluminophosphate (C ₂H₈N)₂[Al₂(HPO₄)(PO ₄₂]

Yu Song, Jihong Yu^*, Yi Li, Guanghua Li, Ruren Xu

^*此作品的通讯作者

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

75 引用（Scopus）

摘要

Solvothermal combinatorial chemistry affords the layered aluminophosphate (C₂H₈N)₂[Al₂(HPO₄) (PO₄)₂]. The macroanionicc layer is based on alternating AlO₄ and PO₄ tetrahedra linked through vertex oxygen atoms to form 4.8-net sheets, stacked in an ABCD sequence along the c axis. The (CH₃)₂NH₂⁺ ions between the inorganic layers interact with the terminal P=O groups to form left- and right-handed helices (see picture) along the b axis.

源语言	英语
页（从-至）	2399-2402
页数	4
期刊	Angewandte Chemie - International Edition
卷	43
期	18
DOI	https://doi.org/10.1002/anie.200353118
出版状态	已出版 - 26 4月 2004
已对外发布	是

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Song, Y., Yu, J., Li, Y., Li, G., & Xu, R. (2004). Hydrogen-bonded helices in the layered aluminophosphate (C ₂H₈N)₂[Al₂(HPO₄)(PO ₄₂]. Angewandte Chemie - International Edition, 43(18), 2399-2402. https://doi.org/10.1002/anie.200353118

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abstract = "Solvothermal combinatorial chemistry affords the layered aluminophosphate (C2H8N)2[Al2(HPO4) (PO4)2]. The macroanionicc layer is based on alternating AlO4 and PO4 tetrahedra linked through vertex oxygen atoms to form 4.8-net sheets, stacked in an ABCD sequence along the c axis. The (CH3)2NH2+ ions between the inorganic layers interact with the terminal P=O groups to form left- and right-handed helices (see picture) along the b axis.",

keywords = "Aluminophosphates, Combinatorial chemistry, Hydrogen bonds, Layered compounds, Template synthesis",

author = "Yu Song and Jihong Yu and Yi Li and Guanghua Li and Ruren Xu",

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AU - Xu, Ruren

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N2 - Solvothermal combinatorial chemistry affords the layered aluminophosphate (C2H8N)2[Al2(HPO4) (PO4)2]. The macroanionicc layer is based on alternating AlO4 and PO4 tetrahedra linked through vertex oxygen atoms to form 4.8-net sheets, stacked in an ABCD sequence along the c axis. The (CH3)2NH2+ ions between the inorganic layers interact with the terminal P=O groups to form left- and right-handed helices (see picture) along the b axis.

AB - Solvothermal combinatorial chemistry affords the layered aluminophosphate (C2H8N)2[Al2(HPO4) (PO4)2]. The macroanionicc layer is based on alternating AlO4 and PO4 tetrahedra linked through vertex oxygen atoms to form 4.8-net sheets, stacked in an ABCD sequence along the c axis. The (CH3)2NH2+ ions between the inorganic layers interact with the terminal P=O groups to form left- and right-handed helices (see picture) along the b axis.

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KW - Combinatorial chemistry

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KW - Layered compounds

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Hydrogen-bonded helices in the layered aluminophosphate (C 2H8N)2[Al2(HPO4)(PO 42]

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Hydrogen-bonded helices in the layered aluminophosphate (C ₂H₈N)₂[Al₂(HPO₄)(PO ₄₂]