High performance La 3Ni 2O 7 cathode prepared by a facile sol-gel method for intermediate temperature solid oxide fuel cells

Zhongliang Lou, Jun Peng, Ningning Dai, Jinshuo Qiao, Yiming Yan, Zhenhua Wang, Jiawei Wang, Kening Sun*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

37 引用 (Scopus)

摘要

La 3Ni 2O 7 oxide has been synthesized by a facile sol-gel method using a nonionic surfactant (EO)106(PO)70(EO)106 tri-block copolymer (Pluronic F127) as the chelating agent. The pure phase of La 3Ni 2O 7 has been obtained by sintering at temperatures of 1100 °C for 12 h. La 3Ni 2O 7 oxide as a cathode presents no visible reaction with an Y 2O 3-stabilized ZrO 2 (YSZ) electrolyte. The electrochemical performance of the prepared oxide as a cathode has been investigated. Area specific resistance of La 3Ni 2O 7 material on YSZ electrolyte is as low as 0.39 Ω cm 2 at 750 °C. Furthermore, an anode-supported single-cell configuration of NiO-YSZ/YSZ/La 3Ni 2O 7 has been achieved a maximum power density of 848 mW cm - 2 at 750 °C. The cell performance was stable under a constant current of 0.6 A cm - 2 for over 30 h at 750 °C. These results therefore suggest that La 3Ni 2O 7 synthesized by this sol-gel method is a highly promising cathode material for applications in IT-SOFCs.

源语言英语
页(从-至)97-100
页数4
期刊Electrochemistry Communications
22
1
DOI
出版状态已出版 - 8月 2012

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