Flexible, high-voltage and free-standing composite polymer electrolyte membrane based on triethylene glycol diacetate-2-propenoic acid butyl ester copolymer for lithium-ion batteries

Qiujun Wang; Wei Li Song; Li Zhen Fan; Yu Song

doi:10.1016/j.memsci.2015.06.041

Flexible, high-voltage and free-standing composite polymer electrolyte membrane based on triethylene glycol diacetate-2-propenoic acid butyl ester copolymer for lithium-ion batteries

Qiujun Wang, Wei Li Song, Li Zhen Fan^*, Yu Song

^*此作品的通讯作者

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38 引用（Scopus）

摘要

Composite polymer electrolytes (CPE) based on triethylene glycol diacetate-2-propenoic acid butyl ester (TEGDA-BA) incorporating Al₂O₃ nanoparticles have been fabricated via in situ polymerization. The CPE have exhibited highly uniform morphology, excellent mechanical property (maximum stress up to ~1.3MPa), high ionic conductivity up to 3.92×10^-3Scm^-1 at 25°C, coupled with very high electrochemical stability (>5.0V vs. Li/Li⁺). The Li^|CPE|Li[Li_1/6Ni_1/4Mn_7/12]O_7/4F_1/4 cells have demonstrated remarkably stable charge/discharge performance and great capacity retention in the potential range of 2.0-4.8V. The unexpected growth of interface resistance has been retarded with the presence of Al₂O₃, indicating the enhancement of the interface stability. The results suggest that the CPE have demonstrated tremendous application potential in high-voltage lithium ion batteries.

源语言	英语
页（从-至）	490-496
页数	7
期刊	Journal of Membrane Science
卷	492
DOI	https://doi.org/10.1016/j.memsci.2015.06.041
出版状态	已出版 - 5 10月 2015
已对外发布	是

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title = "Flexible, high-voltage and free-standing composite polymer electrolyte membrane based on triethylene glycol diacetate-2-propenoic acid butyl ester copolymer for lithium-ion batteries",

abstract = "Composite polymer electrolytes (CPE) based on triethylene glycol diacetate-2-propenoic acid butyl ester (TEGDA-BA) incorporating Al2O3 nanoparticles have been fabricated via in situ polymerization. The CPE have exhibited highly uniform morphology, excellent mechanical property (maximum stress up to ~1.3MPa), high ionic conductivity up to 3.92×10-3Scm-1 at 25°C, coupled with very high electrochemical stability (>5.0V vs. Li/Li+). The Li|CPE|Li[Li1/6Ni1/4Mn7/12]O7/4F1/4 cells have demonstrated remarkably stable charge/discharge performance and great capacity retention in the potential range of 2.0-4.8V. The unexpected growth of interface resistance has been retarded with the presence of Al2O3, indicating the enhancement of the interface stability. The results suggest that the CPE have demonstrated tremendous application potential in high-voltage lithium ion batteries.",

keywords = "Alumina, Composites, Lithium ion batteries, Polymer electrolyte",

author = "Qiujun Wang and Song, {Wei Li} and Fan, {Li Zhen} and Yu Song",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2015",

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doi = "10.1016/j.memsci.2015.06.041",

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T1 - Flexible, high-voltage and free-standing composite polymer electrolyte membrane based on triethylene glycol diacetate-2-propenoic acid butyl ester copolymer for lithium-ion batteries

AU - Wang, Qiujun

AU - Song, Wei Li

AU - Fan, Li Zhen

AU - Song, Yu

PY - 2015/10/5

Y1 - 2015/10/5

N2 - Composite polymer electrolytes (CPE) based on triethylene glycol diacetate-2-propenoic acid butyl ester (TEGDA-BA) incorporating Al2O3 nanoparticles have been fabricated via in situ polymerization. The CPE have exhibited highly uniform morphology, excellent mechanical property (maximum stress up to ~1.3MPa), high ionic conductivity up to 3.92×10-3Scm-1 at 25°C, coupled with very high electrochemical stability (>5.0V vs. Li/Li+). The Li|CPE|Li[Li1/6Ni1/4Mn7/12]O7/4F1/4 cells have demonstrated remarkably stable charge/discharge performance and great capacity retention in the potential range of 2.0-4.8V. The unexpected growth of interface resistance has been retarded with the presence of Al2O3, indicating the enhancement of the interface stability. The results suggest that the CPE have demonstrated tremendous application potential in high-voltage lithium ion batteries.

AB - Composite polymer electrolytes (CPE) based on triethylene glycol diacetate-2-propenoic acid butyl ester (TEGDA-BA) incorporating Al2O3 nanoparticles have been fabricated via in situ polymerization. The CPE have exhibited highly uniform morphology, excellent mechanical property (maximum stress up to ~1.3MPa), high ionic conductivity up to 3.92×10-3Scm-1 at 25°C, coupled with very high electrochemical stability (>5.0V vs. Li/Li+). The Li|CPE|Li[Li1/6Ni1/4Mn7/12]O7/4F1/4 cells have demonstrated remarkably stable charge/discharge performance and great capacity retention in the potential range of 2.0-4.8V. The unexpected growth of interface resistance has been retarded with the presence of Al2O3, indicating the enhancement of the interface stability. The results suggest that the CPE have demonstrated tremendous application potential in high-voltage lithium ion batteries.

KW - Alumina

KW - Composites

KW - Lithium ion batteries

KW - Polymer electrolyte

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DO - 10.1016/j.memsci.2015.06.041

M3 - Article

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SN - 0376-7388

VL - 492

SP - 490

EP - 496

JO - Journal of Membrane Science

JF - Journal of Membrane Science

ER -

Flexible, high-voltage and free-standing composite polymer electrolyte membrane based on triethylene glycol diacetate-2-propenoic acid butyl ester copolymer for lithium-ion batteries

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