Enantioselective cyanosilylation of ketones by a catalytic double-activation method employing chiral lewis acid and achiral N-oxide catalysts

Fuxue Chen; Xiaoming Feng; Bo Qin; Guolin Zhang; Yaozhong Jiang

doi:10.1021/ol034158a

Enantioselective cyanosilylation of ketones by a catalytic double-activation method employing chiral lewis acid and achiral N-oxide catalysts

Fuxue Chen, Xiaoming Feng^*, Bo Qin, Guolin Zhang, Yaozhong Jiang

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

131 引用（Scopus）

摘要

(Matrix presented). Enantioselective addition of TMSCN to ketones is achieved by a catalytic double-activation method using 1a-Ti(IV) complex as the Lewis acid and achiral N-oxide 2 as the Lewis base to activate ketones and TMSCN, respectively.

源语言	英语
页（从-至）	949-952
页数	4
期刊	Organic Letters
卷	5
期	6
DOI	https://doi.org/10.1021/ol034158a
出版状态	已出版 - 20 3月 2003
已对外发布	是

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@article{33074f01fcbb4f8fa66669876200b859,

title = "Enantioselective cyanosilylation of ketones by a catalytic double-activation method employing chiral lewis acid and achiral N-oxide catalysts",

abstract = "(Matrix presented). Enantioselective addition of TMSCN to ketones is achieved by a catalytic double-activation method using 1a-Ti(IV) complex as the Lewis acid and achiral N-oxide 2 as the Lewis base to activate ketones and TMSCN, respectively.",

author = "Fuxue Chen and Xiaoming Feng and Bo Qin and Guolin Zhang and Yaozhong Jiang",

year = "2003",

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T1 - Enantioselective cyanosilylation of ketones by a catalytic double-activation method employing chiral lewis acid and achiral N-oxide catalysts

AU - Chen, Fuxue

AU - Feng, Xiaoming

AU - Qin, Bo

AU - Zhang, Guolin

AU - Jiang, Yaozhong

PY - 2003/3/20

Y1 - 2003/3/20

N2 - (Matrix presented). Enantioselective addition of TMSCN to ketones is achieved by a catalytic double-activation method using 1a-Ti(IV) complex as the Lewis acid and achiral N-oxide 2 as the Lewis base to activate ketones and TMSCN, respectively.

AB - (Matrix presented). Enantioselective addition of TMSCN to ketones is achieved by a catalytic double-activation method using 1a-Ti(IV) complex as the Lewis acid and achiral N-oxide 2 as the Lewis base to activate ketones and TMSCN, respectively.

UR - http://www.scopus.com/inward/record.url?scp=0042681991&partnerID=8YFLogxK

U2 - 10.1021/ol034158a

DO - 10.1021/ol034158a

M3 - Article

C2 - 12633113

AN - SCOPUS:0042681991

SN - 1523-7060

VL - 5

SP - 949

EP - 952

JO - Organic Letters

JF - Organic Letters

IS - 6

ER -

Enantioselective cyanosilylation of ketones by a catalytic double-activation method employing chiral lewis acid and achiral N-oxide catalysts

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