Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al4P5O19 (OH)] [C6H18N2] and [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5

Tao Tian; Yi Li; Wen Fu Yan; Ji Hong Yu; Ru Ren Xu

Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al₄P₅O₁₉ (OH)] [C₆H₁₈N₂] and [Ga₈P₈O₃₂F_5.5] [C₆H₁₈N₂]₂ [H₃O⁺]_1.5

Tao Tian, Yi Li, Wen Fu Yan^*, Ji Hong Yu, Ru Ren Xu

^*此作品的通讯作者

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

A new three-dimensional open-framework aluminophosphate [Al₄P₅O₁₉ (OH)] [C₆H₁₈N₂] (AlPO-MPMD) and a new three-dimensional open-framework gallophosphate [Ga₈P₈O₃₂F_5.5] [C₆H₁₈N₂]₂ [H₃O⁺]_1.5 (GaPO-MPMD) were hydrothermally synthesized with 2-methyl-1, 5-pentamethylene diamine (MPMD) as structure directing agent. These compounds were characterized by single crystal and powder X-ray diffraction (XRD) analyses, TGA-DTA, solid MAS NMR analysis, optical rotation analysis, experimental and simulated vibrational circular dichroism (VCD) analysis. The results confirmed that S type of enantiomer of MPMD was preferredly included in the resulting open-framework of AlPO-MPMD and GaPO-MPMD. The in situ enantiomer (chiral) separation of organic structure directing agent under hydrothermal synthesis was achieved.

源语言	英语
页（从-至）	577-583
页数	7
期刊	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
卷	32
期	3
出版状态	已出版 - 3月 2011
已对外发布	是

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title = "Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al4P5O19 (OH)] [C6H18N2] and [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5",

abstract = "A new three-dimensional open-framework aluminophosphate [Al4P5O19 (OH)] [C6H18N2] (AlPO-MPMD) and a new three-dimensional open-framework gallophosphate [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5 (GaPO-MPMD) were hydrothermally synthesized with 2-methyl-1, 5-pentamethylene diamine (MPMD) as structure directing agent. These compounds were characterized by single crystal and powder X-ray diffraction (XRD) analyses, TGA-DTA, solid MAS NMR analysis, optical rotation analysis, experimental and simulated vibrational circular dichroism (VCD) analysis. The results confirmed that S type of enantiomer of MPMD was preferredly included in the resulting open-framework of AlPO-MPMD and GaPO-MPMD. The in situ enantiomer (chiral) separation of organic structure directing agent under hydrothermal synthesis was achieved.",

keywords = "Chiral separation, Hydrothermal synthesis, Open-framework, Phosphate",

author = "Tao Tian and Yi Li and Yan, {Wen Fu} and Yu, {Ji Hong} and Xu, {Ru Ren}",

year = "2011",

month = mar,

language = "English",

volume = "32",

pages = "577--583",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "3",

}

TY - JOUR

T1 - Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al4P5O19 (OH)] [C6H18N2] and [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5

AU - Tian, Tao

AU - Li, Yi

AU - Yan, Wen Fu

AU - Yu, Ji Hong

AU - Xu, Ru Ren

PY - 2011/3

Y1 - 2011/3

N2 - A new three-dimensional open-framework aluminophosphate [Al4P5O19 (OH)] [C6H18N2] (AlPO-MPMD) and a new three-dimensional open-framework gallophosphate [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5 (GaPO-MPMD) were hydrothermally synthesized with 2-methyl-1, 5-pentamethylene diamine (MPMD) as structure directing agent. These compounds were characterized by single crystal and powder X-ray diffraction (XRD) analyses, TGA-DTA, solid MAS NMR analysis, optical rotation analysis, experimental and simulated vibrational circular dichroism (VCD) analysis. The results confirmed that S type of enantiomer of MPMD was preferredly included in the resulting open-framework of AlPO-MPMD and GaPO-MPMD. The in situ enantiomer (chiral) separation of organic structure directing agent under hydrothermal synthesis was achieved.

AB - A new three-dimensional open-framework aluminophosphate [Al4P5O19 (OH)] [C6H18N2] (AlPO-MPMD) and a new three-dimensional open-framework gallophosphate [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5 (GaPO-MPMD) were hydrothermally synthesized with 2-methyl-1, 5-pentamethylene diamine (MPMD) as structure directing agent. These compounds were characterized by single crystal and powder X-ray diffraction (XRD) analyses, TGA-DTA, solid MAS NMR analysis, optical rotation analysis, experimental and simulated vibrational circular dichroism (VCD) analysis. The results confirmed that S type of enantiomer of MPMD was preferredly included in the resulting open-framework of AlPO-MPMD and GaPO-MPMD. The in situ enantiomer (chiral) separation of organic structure directing agent under hydrothermal synthesis was achieved.

KW - Chiral separation

KW - Hydrothermal synthesis

KW - Open-framework

KW - Phosphate

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M3 - Article

AN - SCOPUS:79955723036

SN - 0251-0790

VL - 32

SP - 577

EP - 583

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 3

ER -

Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al4P5O19 (OH)] [C6H18N2] and [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5

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Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al₄P₅O₁₉ (OH)] [C₆H₁₈N₂] and [Ga₈P₈O₃₂F_5.5] [C₆H₁₈N₂]₂ [H₃O⁺]_1.5