TY - JOUR
T1 - (C6H17N3)[Zn4(PO 4)2(HPO3)2]
T2 - A new layered zinc phosphate-phosphite templated by 1-(2-Aminoethyl) piperazine
AU - Chen, Xiaoxin
AU - Wang, Yu
AU - Yu, Jihong
AU - Zou, Yongchun
AU - Xu, Ruren
PY - 2004/7
Y1 - 2004/7
N2 - Employing 1-(2-Aminoethyl) piperazine as a template, a new organically templated layered zinc phosphate-phosphite (C6H17N 3)[Zn4(PO4)2(HPO3) 2] has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group Cc with a=5.3272(11)Å, b=17.146(3)Å, c=22.071(4)Å, β=94.58(3)°, V=2009.5(7)Å3, Z=4, R1=0.0201 (I>2σ(I)) and wR2=0.0812 (all data). The inorganic network is based on strictly alternating ZnO4 tetrahedral units and P-centered units including PO4 tetrahedra and HPO3 pseudo-pyramids forming a double layered structure that contains columns of double six-membered rings. The diprotonated 1-(2-Aminoethyl) piperazine molecules reside in the interlayer region and interact with the inorganic network through H-bonds.
AB - Employing 1-(2-Aminoethyl) piperazine as a template, a new organically templated layered zinc phosphate-phosphite (C6H17N 3)[Zn4(PO4)2(HPO3) 2] has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group Cc with a=5.3272(11)Å, b=17.146(3)Å, c=22.071(4)Å, β=94.58(3)°, V=2009.5(7)Å3, Z=4, R1=0.0201 (I>2σ(I)) and wR2=0.0812 (all data). The inorganic network is based on strictly alternating ZnO4 tetrahedral units and P-centered units including PO4 tetrahedra and HPO3 pseudo-pyramids forming a double layered structure that contains columns of double six-membered rings. The diprotonated 1-(2-Aminoethyl) piperazine molecules reside in the interlayer region and interact with the inorganic network through H-bonds.
KW - Host-guest system
KW - Hydrothermal synthesis
KW - Layer
KW - Structure
KW - Zinc phosphate-phosphite
UR - http://www.scopus.com/inward/record.url?scp=2942694205&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2004.03.039
DO - 10.1016/j.jssc.2004.03.039
M3 - Article
AN - SCOPUS:2942694205
SN - 0022-4596
VL - 177
SP - 2518
EP - 2522
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 7
ER -