Cocrystallization of energetic Mn(II) complex with nitrogen-rich ligand SCZ and oxygen-rich ligand TNR

Guo Ying Zhang; Li Yang; Wen Chao Tong; Ji Min Han; Nai Meng Song

doi:10.1080/00958972.2019.1575962

Cocrystallization of energetic Mn(II) complex with nitrogen-rich ligand SCZ and oxygen-rich ligand TNR

Guo Ying Zhang, Li Yang^*, Wen Chao Tong, Ji Min Han, Nai Meng Song

^*此作品的通讯作者

机电学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

Based on the advantages of energetic complexes and cocrystallization, a novel energetic complex cocrystal [Mn(SCZ) ₃ ](TNR) (H ₂ O) · [Mn(SCZ) ₂ (H ₂ O)(TNR)](H ₂ O) (SCZ: semicarbazide, TNR: 2,4,6-trinitroresorcinol) was synthesized through a one-step reaction. This cocrystal contains equal units of [Mn(SCZ) ₂ (H ₂ O)(TNR)](H ₂ O) and [Mn(SCZ) ₃ ]TNR(H ₂ O). The molecules of the two units arrange mutually crosswise in the cocrystal and the benzene rings of TNR can form one-dimensional self-assemblies through π-π stacking. The thermal decomposition of the cocrystal is complicated with one endothermic process and three exothermic processes in the DSC curve. The complex [Mn(SCZ) ₂ (H ₂ O)(TNR)] · 3(H ₂ O) was synthesized and the temperature of the major exothermic peak of the cocrystal is higher than observed for this complex.

源语言	英语
页（从-至）	468-479
页数	12
期刊	Journal of Coordination Chemistry
卷	72
期	3
DOI	https://doi.org/10.1080/00958972.2019.1575962
出版状态	已出版 - 1 2月 2019

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Zhang, G. Y., Yang, L., Tong, W. C., Han, J. M., & Song, N. M. (2019). Cocrystallization of energetic Mn(II) complex with nitrogen-rich ligand SCZ and oxygen-rich ligand TNR. Journal of Coordination Chemistry, 72(3), 468-479. https://doi.org/10.1080/00958972.2019.1575962

@article{220d387624cc4f468879fb8f301fa51f,

title = "Cocrystallization of energetic Mn(II) complex with nitrogen-rich ligand SCZ and oxygen-rich ligand TNR",

abstract = " Based on the advantages of energetic complexes and cocrystallization, a novel energetic complex cocrystal [Mn(SCZ) 3 ](TNR) (H 2 O) · [Mn(SCZ) 2 (H 2 O)(TNR)](H 2 O) (SCZ: semicarbazide, TNR: 2,4,6-trinitroresorcinol) was synthesized through a one-step reaction. This cocrystal contains equal units of [Mn(SCZ) 2 (H 2 O)(TNR)](H 2 O) and [Mn(SCZ) 3 ]TNR(H 2 O). The molecules of the two units arrange mutually crosswise in the cocrystal and the benzene rings of TNR can form one-dimensional self-assemblies through π-π stacking. The thermal decomposition of the cocrystal is complicated with one endothermic process and three exothermic processes in the DSC curve. The complex [Mn(SCZ) 2 (H 2 O)(TNR)] · 3(H 2 O) was synthesized and the temperature of the major exothermic peak of the cocrystal is higher than observed for this complex.",

keywords = "Cocrystal, crystal structure, energetic complex",

author = "Zhang, {Guo Ying} and Li Yang and Tong, {Wen Chao} and Han, {Ji Min} and Song, {Nai Meng}",

note = "Publisher Copyright: {\textcopyright} 2019, {\textcopyright} 2019 Informa UK Limited, trading as Taylor & Francis Group.",

year = "2019",

month = feb,

day = "1",

doi = "10.1080/00958972.2019.1575962",

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TY - JOUR

T1 - Cocrystallization of energetic Mn(II) complex with nitrogen-rich ligand SCZ and oxygen-rich ligand TNR

AU - Zhang, Guo Ying

AU - Yang, Li

AU - Tong, Wen Chao

AU - Han, Ji Min

AU - Song, Nai Meng

PY - 2019/2/1

Y1 - 2019/2/1

N2 - Based on the advantages of energetic complexes and cocrystallization, a novel energetic complex cocrystal [Mn(SCZ) 3 ](TNR) (H 2 O) · [Mn(SCZ) 2 (H 2 O)(TNR)](H 2 O) (SCZ: semicarbazide, TNR: 2,4,6-trinitroresorcinol) was synthesized through a one-step reaction. This cocrystal contains equal units of [Mn(SCZ) 2 (H 2 O)(TNR)](H 2 O) and [Mn(SCZ) 3 ]TNR(H 2 O). The molecules of the two units arrange mutually crosswise in the cocrystal and the benzene rings of TNR can form one-dimensional self-assemblies through π-π stacking. The thermal decomposition of the cocrystal is complicated with one endothermic process and three exothermic processes in the DSC curve. The complex [Mn(SCZ) 2 (H 2 O)(TNR)] · 3(H 2 O) was synthesized and the temperature of the major exothermic peak of the cocrystal is higher than observed for this complex.

AB - Based on the advantages of energetic complexes and cocrystallization, a novel energetic complex cocrystal [Mn(SCZ) 3 ](TNR) (H 2 O) · [Mn(SCZ) 2 (H 2 O)(TNR)](H 2 O) (SCZ: semicarbazide, TNR: 2,4,6-trinitroresorcinol) was synthesized through a one-step reaction. This cocrystal contains equal units of [Mn(SCZ) 2 (H 2 O)(TNR)](H 2 O) and [Mn(SCZ) 3 ]TNR(H 2 O). The molecules of the two units arrange mutually crosswise in the cocrystal and the benzene rings of TNR can form one-dimensional self-assemblies through π-π stacking. The thermal decomposition of the cocrystal is complicated with one endothermic process and three exothermic processes in the DSC curve. The complex [Mn(SCZ) 2 (H 2 O)(TNR)] · 3(H 2 O) was synthesized and the temperature of the major exothermic peak of the cocrystal is higher than observed for this complex.

KW - Cocrystal

KW - crystal structure

KW - energetic complex

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DO - 10.1080/00958972.2019.1575962

M3 - Article

AN - SCOPUS:85061912645

SN - 0095-8972

VL - 72

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JO - Journal of Coordination Chemistry

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ER -

Cocrystallization of energetic Mn(II) complex with nitrogen-rich ligand SCZ and oxygen-rich ligand TNR

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