Bis(diethylenetriamine-κ3N)nickel hexafluorogermanate

Hong Xia Zhang; Guo Yu Yang; Yan Qiong Sun

doi:10.1107/S1600536803006160

Bis(diethylenetriamine-κ³N)nickel hexafluorogermanate

Hong Xia Zhang, Guo Yu Yang^*, Yan Qiong Sun

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

The title compound, [Ni(dien)₂][GeF₆] (dien is diethylenetriamine, C₄H₁₃N₃), synthesized under mild solvothermal conditions, is a novel zero-dimensional material in which [GeF₆]^2- building anions are connected to [Ni(dien) ₂]²⁺ cations via hydrogen bonds between F atoms and N-H groups. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one F and one N atom (including the attached H atom) are located on a mirror plane.

源语言	英语
页（从-至）	m185-m187
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	59
期	4
DOI	https://doi.org/10.1107/S1600536803006160
出版状态	已出版 - 4月 2003
已对外发布	是

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Zhang, H. X., Yang, G. Y., & Sun, Y. Q. (2003). Bis(diethylenetriamine-κ³N)nickel hexafluorogermanate. Acta Crystallographica Section E: Structure Reports Online, 59(4), m185-m187. https://doi.org/10.1107/S1600536803006160

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title = "Bis(diethylenetriamine-κ3N)nickel hexafluorogermanate",

abstract = "The title compound, [Ni(dien)2][GeF6] (dien is diethylenetriamine, C4H13N3), synthesized under mild solvothermal conditions, is a novel zero-dimensional material in which [GeF6]2- building anions are connected to [Ni(dien) 2]2+ cations via hydrogen bonds between F atoms and N-H groups. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one F and one N atom (including the attached H atom) are located on a mirror plane.",

author = "Zhang, {Hong Xia} and Yang, {Guo Yu} and Sun, {Yan Qiong}",

year = "2003",

month = apr,

doi = "10.1107/S1600536803006160",

language = "English",

volume = "59",

pages = "m185--m187",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

number = "4",

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T1 - Bis(diethylenetriamine-κ3N)nickel hexafluorogermanate

AU - Zhang, Hong Xia

AU - Yang, Guo Yu

AU - Sun, Yan Qiong

PY - 2003/4

Y1 - 2003/4

N2 - The title compound, [Ni(dien)2][GeF6] (dien is diethylenetriamine, C4H13N3), synthesized under mild solvothermal conditions, is a novel zero-dimensional material in which [GeF6]2- building anions are connected to [Ni(dien) 2]2+ cations via hydrogen bonds between F atoms and N-H groups. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one F and one N atom (including the attached H atom) are located on a mirror plane.

AB - The title compound, [Ni(dien)2][GeF6] (dien is diethylenetriamine, C4H13N3), synthesized under mild solvothermal conditions, is a novel zero-dimensional material in which [GeF6]2- building anions are connected to [Ni(dien) 2]2+ cations via hydrogen bonds between F atoms and N-H groups. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one F and one N atom (including the attached H atom) are located on a mirror plane.

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U2 - 10.1107/S1600536803006160

DO - 10.1107/S1600536803006160

M3 - Article

AN - SCOPUS:18444365947

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VL - 59

SP - m185-m187

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Bis(diethylenetriamine-κ3N)nickel hexafluorogermanate

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Bis(diethylenetriamine-κ³N)nickel hexafluorogermanate