An unprecedented example of a heterotrimetallic main-group [L 2Al2Ge4Li2S7] cluster containing a GeII-GeII donor-acceptor bond

Zhi Yang*, Xiaoli Ma, Rainer B. Oswald, Herbert W. Roesky, Chunming Cui, Hans Georg Schmidt, Mathias Noltemeyer

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

20 引用 (Scopus)

摘要

(Chemical Equation Presented) Donations accepted : The reaction of [{LAl[(SLi)2(thf)2]}2] (L = HC(CMeNAr) 2, Ar = 2,6-iPr2C6H3) with GeCl 2·dioxane yields the novel GeII→Ge II-containing hetero-trimetallic [L2Al2Ge 4Li2S7] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.

源语言英语
页(从-至)2277-2280
页数4
期刊Angewandte Chemie - International Edition
45
14
DOI
出版状态已出版 - 27 3月 2006
已对外发布

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