TY - JOUR
T1 - An open-framework cobalt molybdate possessing {Mo2O7} building block
T2 - Hydrothermal synthesis and structural characterization of [CoMo2O7(4,4′- bipy)1.5]
AU - Wang, Chun Mei
AU - Sun, Yan Qiong
AU - Yang, Guo Yu
PY - 2007/12
Y1 - 2007/12
N2 - The hydrothermal reaction of Co(COO)2·4H2O, MoO3, H3PO4 and 4,4′-bipyridine yields bipyridine-ligated cobalt dimolybdate [CoMo2O7(4,4′-bipy)1.5] (1) (4,4′-bipy = 4,4′-bipyridine) in the triclinic system with space group of P 1 and cell parameters of a = 7.1951(8) Å, b = 11.1708(17) Å, c = 11.4514(11) Å, α = 98.545(7)°, β = 90.315(2)°, γ = 105.777(5)°, V = 874.88(19) Å3, and Z = 2. Its structure consists of Co/Mo/O bimetal oxide layers with {Mo2O7} building blocks, linked by the coordination of 4,4′-bipy ligand with Co and Mo atoms, into a 3D porous hybrid framework.
AB - The hydrothermal reaction of Co(COO)2·4H2O, MoO3, H3PO4 and 4,4′-bipyridine yields bipyridine-ligated cobalt dimolybdate [CoMo2O7(4,4′-bipy)1.5] (1) (4,4′-bipy = 4,4′-bipyridine) in the triclinic system with space group of P 1 and cell parameters of a = 7.1951(8) Å, b = 11.1708(17) Å, c = 11.4514(11) Å, α = 98.545(7)°, β = 90.315(2)°, γ = 105.777(5)°, V = 874.88(19) Å3, and Z = 2. Its structure consists of Co/Mo/O bimetal oxide layers with {Mo2O7} building blocks, linked by the coordination of 4,4′-bipy ligand with Co and Mo atoms, into a 3D porous hybrid framework.
KW - Cobalt molybdate
KW - Crystal structure
KW - Hydrothermal synthesis
KW - Open-framework
UR - http://www.scopus.com/inward/record.url?scp=35348898349&partnerID=8YFLogxK
U2 - 10.1080/00958970701286466
DO - 10.1080/00958970701286466
M3 - Article
AN - SCOPUS:35348898349
SN - 0095-8972
VL - 60
SP - 2629
EP - 2636
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 23
ER -