Addition of carbene to the equator of C70 to produce the most stable C71H2 isomer: 2aH-2(12)a-homo(C7o-D 5h(6))[5,6]fullerene

Bao Li*, Chunying Shu, Xin Lu, Lothar Dunsch, Zhongfang Chen, T. John S. Dennis, Zhiqiang Shi, Li Jiang, Taishan Wang, Wei Xu, Chunru Wang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

28 引用 (Scopus)

摘要

(Figure Presented) At long last, the elusive thermodynamically most stable isomer of C71,H2 (see structure) has been synthesized through the addition of CH2 across an equatorial bond Of C 70: a site at which sucha reaction is not kinetically favorable. Theoretical studies revealed that the pyrogenic synthetic method used enables reactants to overcome the higher activation barrier to equatorial addition.

源语言英语
页(从-至)962-966
页数5
期刊Angewandte Chemie - International Edition
49
5
DOI
出版状态已出版 - 25 1月 2010
已对外发布

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