A supramolecular approach for the synthesis of cross-linked ionic polyacetylene network gels

Yong Tian; Lingwei Kong; Huiling Mao; Jianbing Shi; Bin Tong; Zhengxu Cai; Yuping Dong

doi:10.1039/c9qm00577c

A supramolecular approach for the synthesis of cross-linked ionic polyacetylene network gels

Yong Tian, Lingwei Kong, Huiling Mao, Jianbing Shi, Bin Tong, Zhengxu Cai^*, Yuping Dong

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

The poly((para-(4-methylpiperazin-1-yl)methanone)phenylacetylene) (PPA) polymer with a 66% trans-cisoid configuration was used to prepare a π-conjugated ionic polyacetylene network gel (π-IPN gel) by a simple cross-linking reaction between PPA and suberic acid in an appropriate functional group ratio. The PPA hydrogel could be synthesized in bulk quantities with a uniform morphology of self-assembled interconnected nanospheres. In addition, experimental results revealed that the PPA-based π-IPN gel led to an enhanced electrical storage ability and demonstrated immense potential for use in flexible solid-state energy storage devices.

源语言	英语
页（从-至）	645-650
页数	6
期刊	Materials Chemistry Frontiers
卷	4
期	2
DOI	https://doi.org/10.1039/c9qm00577c
出版状态	已出版 - 2月 2020

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abstract = "The poly((para-(4-methylpiperazin-1-yl)methanone)phenylacetylene) (PPA) polymer with a 66% trans-cisoid configuration was used to prepare a π-conjugated ionic polyacetylene network gel (π-IPN gel) by a simple cross-linking reaction between PPA and suberic acid in an appropriate functional group ratio. The PPA hydrogel could be synthesized in bulk quantities with a uniform morphology of self-assembled interconnected nanospheres. In addition, experimental results revealed that the PPA-based π-IPN gel led to an enhanced electrical storage ability and demonstrated immense potential for use in flexible solid-state energy storage devices.",

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AU - Tian, Yong

AU - Kong, Lingwei

AU - Mao, Huiling

AU - Shi, Jianbing

AU - Tong, Bin

AU - Cai, Zhengxu

AU - Dong, Yuping

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N2 - The poly((para-(4-methylpiperazin-1-yl)methanone)phenylacetylene) (PPA) polymer with a 66% trans-cisoid configuration was used to prepare a π-conjugated ionic polyacetylene network gel (π-IPN gel) by a simple cross-linking reaction between PPA and suberic acid in an appropriate functional group ratio. The PPA hydrogel could be synthesized in bulk quantities with a uniform morphology of self-assembled interconnected nanospheres. In addition, experimental results revealed that the PPA-based π-IPN gel led to an enhanced electrical storage ability and demonstrated immense potential for use in flexible solid-state energy storage devices.

AB - The poly((para-(4-methylpiperazin-1-yl)methanone)phenylacetylene) (PPA) polymer with a 66% trans-cisoid configuration was used to prepare a π-conjugated ionic polyacetylene network gel (π-IPN gel) by a simple cross-linking reaction between PPA and suberic acid in an appropriate functional group ratio. The PPA hydrogel could be synthesized in bulk quantities with a uniform morphology of self-assembled interconnected nanospheres. In addition, experimental results revealed that the PPA-based π-IPN gel led to an enhanced electrical storage ability and demonstrated immense potential for use in flexible solid-state energy storage devices.

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A supramolecular approach for the synthesis of cross-linked ionic polyacetylene network gels

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