A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)

Min Jie Wu; Shu Sen Chen; Shao Hua Jin; Li Jie Li

doi:10.3969/j.issn.1006-9941.2013.02.024

A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)

Min Jie Wu^*, Shu Sen Chen, Shao Hua Jin, Li Jie Li

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

5 引用（Scopus）

摘要

A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF) which used 3, 4-diaminofurazan as raw material and 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan as intermediate was introduced. 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan was oxygenating by 30% H₂O₂ in solvent of 1, 4-dioxane. After refluxing for 4 h, DAOAF was obtainded with yield 97% or 89%. The product was characterized by ¹H NMR, ¹³C NMR, IR and EI.

源语言	英语
页（从-至）	273-275
页数	3
期刊	Hanneng Cailiao/Chinese Journal of Energetic Materials
卷	21
期	2
DOI	https://doi.org/10.3969/j.issn.1006-9941.2013.02.024
出版状态	已出版 - 4月 2013

访问文件

10.3969/j.issn.1006-9941.2013.02.024

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{d528be8e66904333bce920f2d3ca9ba1,

title = "A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)",

abstract = "A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF) which used 3, 4-diaminofurazan as raw material and 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan as intermediate was introduced. 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan was oxygenating by 30% H2O2 in solvent of 1, 4-dioxane. After refluxing for 4 h, DAOAF was obtainded with yield 97% or 89%. The product was characterized by 1H NMR, 13C NMR, IR and EI.",

keywords = "3'-diamino-4, 4'-azoxyfurazan, 3, 4-diaminofurazan, 3-amino-4-formylaminofurazan, Organic chemistry, Synthesis",

author = "Wu, {Min Jie} and Chen, {Shu Sen} and Jin, {Shao Hua} and Li, {Li Jie}",

year = "2013",

month = apr,

doi = "10.3969/j.issn.1006-9941.2013.02.024",

language = "English",

volume = "21",

pages = "273--275",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "2",

}

TY - JOUR

T1 - A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)

AU - Wu, Min Jie

AU - Chen, Shu Sen

AU - Jin, Shao Hua

AU - Li, Li Jie

PY - 2013/4

Y1 - 2013/4

N2 - A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF) which used 3, 4-diaminofurazan as raw material and 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan as intermediate was introduced. 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan was oxygenating by 30% H2O2 in solvent of 1, 4-dioxane. After refluxing for 4 h, DAOAF was obtainded with yield 97% or 89%. The product was characterized by 1H NMR, 13C NMR, IR and EI.

AB - A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF) which used 3, 4-diaminofurazan as raw material and 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan as intermediate was introduced. 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan was oxygenating by 30% H2O2 in solvent of 1, 4-dioxane. After refluxing for 4 h, DAOAF was obtainded with yield 97% or 89%. The product was characterized by 1H NMR, 13C NMR, IR and EI.

KW - 3'-diamino-4, 4'-azoxyfurazan

KW - 3, 4-diaminofurazan

KW - 3-amino-4-formylaminofurazan

KW - Organic chemistry

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=84878756476&partnerID=8YFLogxK

U2 - 10.3969/j.issn.1006-9941.2013.02.024

DO - 10.3969/j.issn.1006-9941.2013.02.024

M3 - Article

AN - SCOPUS:84878756476

SN - 1006-9941

VL - 21

SP - 273

EP - 275

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 2

ER -

A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)

摘要

访问文件

其它文件与链接

指纹

引用此