摘要
The reaction of sodium metal with Cp 2ZrCl 2 and RGaCl 2 in hexane affords Cp 2Zr(GaR) 2 (R = -C 6H 3-2,6-(2,4,6-i-Pr 3C 6H 2) 2) as deep green-black air-sensitive crystals. Essentially, Cp 2Zr(GaR) 2 is isoelectronic with the well-known 18-electron zirconocene dicarbonyl, Cp 2-Zr(CO) 2, complex. The title compound is the first example of an organometallic compound containing Ga-Zr bonds (Ga-Zr = 2.6350(8) Å).
源语言 | 英语 |
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页(从-至) | 5119-5120 |
页数 | 2 |
期刊 | Organometallics |
卷 | 23 |
期 | 22 |
DOI | |
出版状态 | 已出版 - 25 10月 2004 |
已对外发布 | 是 |