A highly stable octa-coordinated energetic complex

Wenchao Tong; Mei Bian; Yongan Feng; Tonglai Zhang; Shuangqi Hu; Li Yang

doi:10.1039/d0ce01008a

A highly stable octa-coordinated energetic complex

Wenchao Tong, Mei Bian, Yongan Feng, Tonglai Zhang, Shuangqi Hu, Li Yang^*

^*此作品的通讯作者

机电学院

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.

源语言	英语
页（从-至）	6591-6595
页数	5
期刊	CrystEngComm
卷	22
期	40
DOI	https://doi.org/10.1039/d0ce01008a
出版状态	已出版 - 28 10月 2020

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Tong, W., Bian, M., Feng, Y., Zhang, T., Hu, S., & Yang, L. (2020). A highly stable octa-coordinated energetic complex. CrystEngComm, 22(40), 6591-6595. https://doi.org/10.1039/d0ce01008a

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title = "A highly stable octa-coordinated energetic complex",

abstract = "The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.",

author = "Wenchao Tong and Mei Bian and Yongan Feng and Tonglai Zhang and Shuangqi Hu and Li Yang",

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AU - Tong, Wenchao

AU - Bian, Mei

AU - Feng, Yongan

AU - Zhang, Tonglai

AU - Hu, Shuangqi

AU - Yang, Li

PY - 2020/10/28

Y1 - 2020/10/28

N2 - The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.

AB - The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.

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A highly stable octa-coordinated energetic complex

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