A gallogermanate zeolite with eleven-membered-ring channels

Yan Xu; Yi Li; Yide Han; Xiaowei Song; Jihong Yu

doi:10.1002/anie.201300846

A gallogermanate zeolite with eleven-membered-ring channels

Yan Xu, Yi Li, Yide Han, Xiaowei Song, Jihong Yu

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

40 引用（Scopus）

摘要

Ring the change: The gallogermanate zeolite |(Ni(C₃H ₁₀N₂)₃)₃₆Ni_4.7|[Ga _81.4Ge_206.6O₅₇₆], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [3¹².4³.6².11⁶] cavities, induced by chiral [Ni(1,2-PDA)₃]²⁺ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

源语言	英语
页（从-至）	5501-5503
页数	3
期刊	Angewandte Chemie - International Edition
卷	52
期	21
DOI	https://doi.org/10.1002/anie.201300846
出版状态	已出版 - 17 5月 2013
已对外发布	是

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Xu, Y., Li, Y., Han, Y., Song, X., & Yu, J. (2013). A gallogermanate zeolite with eleven-membered-ring channels. Angewandte Chemie - International Edition, 52(21), 5501-5503. https://doi.org/10.1002/anie.201300846

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abstract = "Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.",

keywords = "enantiomers, gallogermanates, low framework density, template synthesis, zeolite analogues",

author = "Yan Xu and Yi Li and Yide Han and Xiaowei Song and Jihong Yu",

year = "2013",

month = may,

day = "17",

doi = "10.1002/anie.201300846",

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AU - Xu, Yan

AU - Li, Yi

AU - Han, Yide

AU - Song, Xiaowei

AU - Yu, Jihong

PY - 2013/5/17

Y1 - 2013/5/17

N2 - Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

AB - Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

KW - enantiomers

KW - gallogermanates

KW - low framework density

KW - template synthesis

KW - zeolite analogues

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A gallogermanate zeolite with eleven-membered-ring channels

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