Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex

Jun Tao; Hiroyuki Maruyama; Osamu Sato

doi:10.1021/ja057488u

Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex

Jun Tao, Hiroyuki Maruyama, Osamu Sato^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

189 Citations (Scopus)

Abstract

A dinuclear complex, [(CoTPA)₂(DHBQ)](PF₆)₃, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.

Original language	English
Pages (from-to)	1790-1791
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	6
DOIs	https://doi.org/10.1021/ja057488u
Publication status	Published - 15 Feb 2006
Externally published	Yes

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@article{a33463e4621c4e7c980d952339317927,

title = "Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex",

abstract = "A dinuclear complex, [(CoTPA)2(DHBQ)](PF6)3, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.",

author = "Jun Tao and Hiroyuki Maruyama and Osamu Sato",

year = "2006",

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doi = "10.1021/ja057488u",

language = "English",

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journal = "Journal of the American Chemical Society",

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T1 - Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex

AU - Tao, Jun

AU - Maruyama, Hiroyuki

AU - Sato, Osamu

PY - 2006/2/15

Y1 - 2006/2/15

N2 - A dinuclear complex, [(CoTPA)2(DHBQ)](PF6)3, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.

AB - A dinuclear complex, [(CoTPA)2(DHBQ)](PF6)3, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.

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U2 - 10.1021/ja057488u

DO - 10.1021/ja057488u

M3 - Article

AN - SCOPUS:33244472159

SN - 0002-7863

VL - 128

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 6

ER -

Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex

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