Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex

Ya Dong Lu; Yan Hua Wang; Zi Lin Jin

Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex

Ya Dong Lu^*, Yan Hua Wang, Zi Lin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H₂)=5.0MPa, T=80°C, t=3h, 1-octene/Ru=1000 (molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.

Original language	English
Pages (from-to)	255-257
Number of pages	3
Journal	Chinese Chemical Letters
Volume	17
Issue number	2
Publication status	Published - Feb 2006
Externally published	Yes

Keywords

1-octene
Hydrogenation
Ruthenium
Thermoregulated organic biphasic system

Cite this

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title = "Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex",

abstract = "Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H2)=5.0MPa, T=80°C, t=3h, 1-octene/Ru=1000 (molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.",

keywords = "1-octene, Hydrogenation, Ruthenium, Thermoregulated organic biphasic system",

author = "Lu, {Ya Dong} and Wang, {Yan Hua} and Jin, {Zi Lin}",

year = "2006",

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language = "English",

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pages = "255--257",

journal = "Chinese Chemical Letters",

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T1 - Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex

AU - Lu, Ya Dong

AU - Wang, Yan Hua

AU - Jin, Zi Lin

PY - 2006/2

Y1 - 2006/2

N2 - Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H2)=5.0MPa, T=80°C, t=3h, 1-octene/Ru=1000 (molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.

AB - Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H2)=5.0MPa, T=80°C, t=3h, 1-octene/Ru=1000 (molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.

KW - 1-octene

KW - Hydrogenation

KW - Ruthenium

KW - Thermoregulated organic biphasic system

UR - http://www.scopus.com/inward/record.url?scp=33644695445&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33644695445

SN - 1001-8417

VL - 17

SP - 255

EP - 257

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 2

ER -

Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex

Abstract

Keywords

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