Tetrakis(μ-a-naphthylacetato-/k2O:O′)bis-[(dimethyl sulfoxide-kO)copper(II)]-a-naphthylacetic acid-dimethyl sulfoxide (1/2/2)

Lan Fen Chen; Jie Zhang; Li Jun Song; Wen Guo Wang; Zhan Feng Ju

doi:10.1107/S1600536804015284

Tetrakis(μ-a-naphthylacetato-/k²O:O′)bis-[(dimethyl sulfoxide-kO)copper(II)]-a-naphthylacetic acid-dimethyl sulfoxide (1/2/2)

Lan Fen Chen, Jie Zhang^*, Li Jun Song, Wen Guo Wang, Zhan Feng Ju

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The title complex, [Cu₂(NAA)₄(DMSO) ₂]·2(HNAA)·-2DMSO [NAA = α-naphthylacetate (C₁₂H₉O₂) and DMSO = dimethyl sulfoxide (C ₂H₆OS)], consists of a centrosymmetric dinuclear cage unit, in which two Cu^II atoms are separated by 2.626 (1) Å and bridged by four bidentate carboxylate groups of naphthylacetales, with an average Cu-O distance of 1.961 (2) Å. Each Cu^II atom has a five-coordinate square-pyramidal environment with the dimethyl sulfoxide molecule at the apical position. The Cu-O bond length to the DMSO molecule is 2.160 (2) Å.

Original language	English
Pages (from-to)	m1032-m1034
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	7
DOIs	https://doi.org/10.1107/S1600536804015284
Publication status	Published - Jul 2004
Externally published	Yes

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title = "Tetrakis(μ-a-naphthylacetato-/k2O:O′)bis-[(dimethyl sulfoxide-kO)copper(II)]-a-naphthylacetic acid-dimethyl sulfoxide (1/2/2)",

abstract = "The title complex, [Cu2(NAA)4(DMSO) 2]·2(HNAA)·-2DMSO [NAA = α-naphthylacetate (C12H9O2) and DMSO = dimethyl sulfoxide (C 2H6OS)], consists of a centrosymmetric dinuclear cage unit, in which two CuII atoms are separated by 2.626 (1) {\AA} and bridged by four bidentate carboxylate groups of naphthylacetales, with an average Cu-O distance of 1.961 (2) {\AA}. Each CuII atom has a five-coordinate square-pyramidal environment with the dimethyl sulfoxide molecule at the apical position. The Cu-O bond length to the DMSO molecule is 2.160 (2) {\AA}.",

author = "Chen, {Lan Fen} and Jie Zhang and Song, {Li Jun} and Wang, {Wen Guo} and Ju, {Zhan Feng}",

year = "2004",

month = jul,

doi = "10.1107/S1600536804015284",

language = "English",

volume = "60",

pages = "m1032--m1034",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

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TY - JOUR

T1 - Tetrakis(μ-a-naphthylacetato-/k2O:O′)bis-[(dimethyl sulfoxide-kO)copper(II)]-a-naphthylacetic acid-dimethyl sulfoxide (1/2/2)

AU - Chen, Lan Fen

AU - Zhang, Jie

AU - Song, Li Jun

AU - Wang, Wen Guo

AU - Ju, Zhan Feng

PY - 2004/7

Y1 - 2004/7

N2 - The title complex, [Cu2(NAA)4(DMSO) 2]·2(HNAA)·-2DMSO [NAA = α-naphthylacetate (C12H9O2) and DMSO = dimethyl sulfoxide (C 2H6OS)], consists of a centrosymmetric dinuclear cage unit, in which two CuII atoms are separated by 2.626 (1) Å and bridged by four bidentate carboxylate groups of naphthylacetales, with an average Cu-O distance of 1.961 (2) Å. Each CuII atom has a five-coordinate square-pyramidal environment with the dimethyl sulfoxide molecule at the apical position. The Cu-O bond length to the DMSO molecule is 2.160 (2) Å.

AB - The title complex, [Cu2(NAA)4(DMSO) 2]·2(HNAA)·-2DMSO [NAA = α-naphthylacetate (C12H9O2) and DMSO = dimethyl sulfoxide (C 2H6OS)], consists of a centrosymmetric dinuclear cage unit, in which two CuII atoms are separated by 2.626 (1) Å and bridged by four bidentate carboxylate groups of naphthylacetales, with an average Cu-O distance of 1.961 (2) Å. Each CuII atom has a five-coordinate square-pyramidal environment with the dimethyl sulfoxide molecule at the apical position. The Cu-O bond length to the DMSO molecule is 2.160 (2) Å.

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U2 - 10.1107/S1600536804015284

DO - 10.1107/S1600536804015284

M3 - Article

AN - SCOPUS:18444408411

SN - 1600-5368

VL - 60

SP - m1032-m1034

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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ER -

Tetrakis(μ-a-naphthylacetato-/k²O:O′)bis-[(dimethyl sulfoxide-kO)copper(II)]-a-naphthylacetic acid-dimethyl sulfoxide (1/2/2)

Abstract

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