TY - JOUR
T1 - Synthesis of Z-1,1,1,4,4,4-hexafluoro-2-butene from hexachlorobutadiene
AU - Zhang, Chengping
AU - Jia, Xiaoqing
AU - Quan, Hengdao
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2016/11/1
Y1 - 2016/11/1
N2 - A novel synthetic route of Z-1,1,1,4,4,4-hexafluoro-2-butene (Z-HFO-1336mzz)was developed. It contains three-step reactions as follows: (1) The vapor-phase catalytic fluorination from hexachlorobutadiene to (E/Z)-2,3-dichlorohexafluoro-2-butenepromoted by Cr-based catalyst; (2) The liquid-phase dechlorination reaction from (E/Z)-2,3-dichlorohexafluoro-2-butene to 1,1,1,4,4,4-hexafluoro-2-butyne with Zn in DMF; (3) The gas-phase hydrogenation reaction from 1,1,1,4,4,4-hexafluoro-2-butyne to Z-HFO-1336mzz promoted by Pd + Bi/PAF (porous aluminium fluoride) catalyst. It provided a potential method for industrial production of Z-HFO-1336mzz.
AB - A novel synthetic route of Z-1,1,1,4,4,4-hexafluoro-2-butene (Z-HFO-1336mzz)was developed. It contains three-step reactions as follows: (1) The vapor-phase catalytic fluorination from hexachlorobutadiene to (E/Z)-2,3-dichlorohexafluoro-2-butenepromoted by Cr-based catalyst; (2) The liquid-phase dechlorination reaction from (E/Z)-2,3-dichlorohexafluoro-2-butene to 1,1,1,4,4,4-hexafluoro-2-butyne with Zn in DMF; (3) The gas-phase hydrogenation reaction from 1,1,1,4,4,4-hexafluoro-2-butyne to Z-HFO-1336mzz promoted by Pd + Bi/PAF (porous aluminium fluoride) catalyst. It provided a potential method for industrial production of Z-HFO-1336mzz.
KW - Chlorofluorination
KW - Dechlorination
KW - Hexachlorobutadiene
KW - Hydrogenation
KW - Z-1,1,1,4,4,4-hexafluoro-2-butene
UR - http://www.scopus.com/inward/record.url?scp=84989298227&partnerID=8YFLogxK
U2 - 10.1016/j.jfluchem.2016.09.012
DO - 10.1016/j.jfluchem.2016.09.012
M3 - Article
AN - SCOPUS:84989298227
SN - 0022-1139
VL - 191
SP - 77
EP - 83
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
ER -