Synthesis and structure of [Cu2(μ-NO2)(aepy) 4] (ClO4)3 (aepy = 2-(2-aminoethyl)pyridine)

Jia Cheng Liu; Guo Cong Guo; Shan Huo Lin; Fa Kun Zheng; Hong Wei Ma; Guo Wei Zhou; Jin Shun Huang

Synthesis and structure of [Cu₂(μ-NO₂)(aepy) ₄] (ClO₄)₃ (aepy = 2-(2-aminoethyl)pyridine)

Jia Cheng Liu, Guo Cong Guo^*, Shan Huo Lin, Fa Kun Zheng, Hong Wei Ma, Guo Wei Zhou, Jin Shun Huang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound [Cu₂(μ-NO²)(aepy) ₄](ClO₄)₃ (Cu₂C₂₈H ₄₀N₉Cl₃O₁₄, M_r = 960.12, aepy = 2-(2-aminoethyl)pyridine) was synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in monoclinic, space group C2/c with cell parameters: a = 21.958(3), b = 12.205(2), c = 15.180(3) Å, β= 106.06(1)°, V = 3909.5(12) Å³, Z = 4, D_c = 1.631 g/cm³, F(000) = 1968 and μ(MoKα) = 1.368 mm^-1. The structure was solved by direct methods and refined by full-matrix least-squares techniques. The final R = 0.0734 and wR = 0.1954 for 1606 observed reflections with I ≥2.0σ(I). The crystal structure revealed that the [Cu₂(μ-NO₂)(aepy)₄] ³⁺ cation consists of two square-based pyramidal copper (II) atoms bridged by one nitrate anion. The distance between the two copper atoms (Cu(1)⋯Cu(1A)) is 5.373 (2) Å.

Original language	English
Pages (from-to)	485-488
Number of pages	4
Journal	Jiegou Huaxue
Volume	21
Issue number	5
Publication status	Published - 2002
Externally published	Yes

Keywords

2-(2-aminoethyl)pyridine
Copper
Crystal structure
Synthesis

Cite this

@article{44f898535c034582888a552570bf1fe9,

title = "Synthesis and structure of [Cu2(μ-NO2)(aepy) 4] (ClO4)3 (aepy = 2-(2-aminoethyl)pyridine)",

abstract = "The title compound [Cu2(μ-NO2)(aepy) 4](ClO4)3 (Cu2C28H 40N9Cl3O14, Mr = 960.12, aepy = 2-(2-aminoethyl)pyridine) was synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in monoclinic, space group C2/c with cell parameters: a = 21.958(3), b = 12.205(2), c = 15.180(3) {\AA}, β= 106.06(1)°, V = 3909.5(12) {\AA}3, Z = 4, Dc = 1.631 g/cm3, F(000) = 1968 and μ(MoKα) = 1.368 mm-1. The structure was solved by direct methods and refined by full-matrix least-squares techniques. The final R = 0.0734 and wR = 0.1954 for 1606 observed reflections with I ≥2.0σ(I). The crystal structure revealed that the [Cu2(μ-NO2)(aepy)4] 3+ cation consists of two square-based pyramidal copper (II) atoms bridged by one nitrate anion. The distance between the two copper atoms (Cu(1)⋯Cu(1A)) is 5.373 (2) {\AA}.",

keywords = "2-(2-aminoethyl)pyridine, Copper, Crystal structure, Synthesis",

author = "Liu, {Jia Cheng} and Guo, {Guo Cong} and Lin, {Shan Huo} and Zheng, {Fa Kun} and Ma, {Hong Wei} and Zhou, {Guo Wei} and Huang, {Jin Shun}",

year = "2002",

language = "English",

volume = "21",

pages = "485--488",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "5",

}

TY - JOUR

T1 - Synthesis and structure of [Cu2(μ-NO2)(aepy) 4] (ClO4)3 (aepy = 2-(2-aminoethyl)pyridine)

AU - Liu, Jia Cheng

AU - Guo, Guo Cong

AU - Lin, Shan Huo

AU - Zheng, Fa Kun

AU - Ma, Hong Wei

AU - Zhou, Guo Wei

AU - Huang, Jin Shun

PY - 2002

Y1 - 2002

N2 - The title compound [Cu2(μ-NO2)(aepy) 4](ClO4)3 (Cu2C28H 40N9Cl3O14, Mr = 960.12, aepy = 2-(2-aminoethyl)pyridine) was synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in monoclinic, space group C2/c with cell parameters: a = 21.958(3), b = 12.205(2), c = 15.180(3) Å, β= 106.06(1)°, V = 3909.5(12) Å3, Z = 4, Dc = 1.631 g/cm3, F(000) = 1968 and μ(MoKα) = 1.368 mm-1. The structure was solved by direct methods and refined by full-matrix least-squares techniques. The final R = 0.0734 and wR = 0.1954 for 1606 observed reflections with I ≥2.0σ(I). The crystal structure revealed that the [Cu2(μ-NO2)(aepy)4] 3+ cation consists of two square-based pyramidal copper (II) atoms bridged by one nitrate anion. The distance between the two copper atoms (Cu(1)⋯Cu(1A)) is 5.373 (2) Å.

AB - The title compound [Cu2(μ-NO2)(aepy) 4](ClO4)3 (Cu2C28H 40N9Cl3O14, Mr = 960.12, aepy = 2-(2-aminoethyl)pyridine) was synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in monoclinic, space group C2/c with cell parameters: a = 21.958(3), b = 12.205(2), c = 15.180(3) Å, β= 106.06(1)°, V = 3909.5(12) Å3, Z = 4, Dc = 1.631 g/cm3, F(000) = 1968 and μ(MoKα) = 1.368 mm-1. The structure was solved by direct methods and refined by full-matrix least-squares techniques. The final R = 0.0734 and wR = 0.1954 for 1606 observed reflections with I ≥2.0σ(I). The crystal structure revealed that the [Cu2(μ-NO2)(aepy)4] 3+ cation consists of two square-based pyramidal copper (II) atoms bridged by one nitrate anion. The distance between the two copper atoms (Cu(1)⋯Cu(1A)) is 5.373 (2) Å.

KW - 2-(2-aminoethyl)pyridine

KW - Copper

KW - Crystal structure

KW - Synthesis

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M3 - Article

AN - SCOPUS:33750371635

SN - 0254-5861

VL - 21

SP - 485

EP - 488

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 5

ER -

Synthesis and structure of [Cu₂(μ-NO₂)(aepy) ₄] (ClO₄)₃ (aepy = 2-(2-aminoethyl)pyridine)

Abstract

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