Synthesis and Structure of a Novel Cyano-bridged Compound SmFe(CN)6(DMSO)2·H2O

Chun Yang; Guo Cong Guo; Hong Wei Ma; Jia Cheng Liu; Xing Zhang; Fa Kun Zheng; Shan Huo Lin; Guo Wei Zhou; Jiang Gao Mao; Jin-Shun Huang Jin-Shun

Synthesis and Structure of a Novel Cyano-bridged Compound SmFe(CN)₆(DMSO)₂·H₂O

Chun Yang, Guo Cong Guo^*, Hong Wei Ma, Jia Cheng Liu, Xing Zhang, Fa Kun Zheng, Shan Huo Lin, Guo Wei Zhou, Jiang Gao Mao, Jin-Shun Huang Jin-Shun

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound SmFe(CN)₆(DMSO)₂·H₂O was prepared by the reaction of SmCl₃·6H₂O with K₃Fe(CN)₆ in the mixed solvent of H₂O/EtOH/DMSO. The crystal of the compound is monoclinic, space group P2/n, a = 7.759(1), b = 10.673(1), c = 11.014(2) Å, β = 97.106(2)°, V= 905.0(2) Å³, Z = 2, D_c = 1.969g/cm³, F (000) = 520, R = 0.0474, wR = 0.0925. The compound is cyano-bridged rare earth transition metallic complex. The rare earth ion (Sm³⁴) is seven-coordinated with the conformation of pentagonal bipyramid. The structure of the compound can be described as a square brick stair-like layered structure, which stacks along b axis with hydrogen bond interaction between the layers to form 3D-network structure.

Original language	English
Pages (from-to)	231-232
Number of pages	2
Journal	Jiegou Huaxue
Volume	20
Issue number	3
Publication status	Published - 2001
Externally published	Yes

Keywords

Crystal structure
Cyano-bridged
Iron
Rare earth

Cite this

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title = "Synthesis and Structure of a Novel Cyano-bridged Compound SmFe(CN)6(DMSO)2·H2O",

abstract = "The title compound SmFe(CN)6(DMSO)2·H2O was prepared by the reaction of SmCl3·6H2O with K3Fe(CN)6 in the mixed solvent of H2O/EtOH/DMSO. The crystal of the compound is monoclinic, space group P2/n, a = 7.759(1), b = 10.673(1), c = 11.014(2) {\AA}, β = 97.106(2)°, V= 905.0(2) {\AA}3, Z = 2, Dc = 1.969g/cm3, F (000) = 520, R = 0.0474, wR = 0.0925. The compound is cyano-bridged rare earth transition metallic complex. The rare earth ion (Sm34) is seven-coordinated with the conformation of pentagonal bipyramid. The structure of the compound can be described as a square brick stair-like layered structure, which stacks along b axis with hydrogen bond interaction between the layers to form 3D-network structure.",

keywords = "Crystal structure, Cyano-bridged, Iron, Rare earth",

author = "Chun Yang and Guo, {Guo Cong} and Ma, {Hong Wei} and Liu, {Jia Cheng} and Xing Zhang and Zheng, {Fa Kun} and Lin, {Shan Huo} and Zhou, {Guo Wei} and Mao, {Jiang Gao} and {Huang Jin-Shun}, Jin-Shun",

year = "2001",

language = "English",

volume = "20",

pages = "231--232",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "3",

}

TY - JOUR

T1 - Synthesis and Structure of a Novel Cyano-bridged Compound SmFe(CN)6(DMSO)2·H2O

AU - Yang, Chun

AU - Guo, Guo Cong

AU - Ma, Hong Wei

AU - Liu, Jia Cheng

AU - Zhang, Xing

AU - Zheng, Fa Kun

AU - Lin, Shan Huo

AU - Zhou, Guo Wei

AU - Mao, Jiang Gao

AU - Huang Jin-Shun, Jin-Shun

PY - 2001

Y1 - 2001

N2 - The title compound SmFe(CN)6(DMSO)2·H2O was prepared by the reaction of SmCl3·6H2O with K3Fe(CN)6 in the mixed solvent of H2O/EtOH/DMSO. The crystal of the compound is monoclinic, space group P2/n, a = 7.759(1), b = 10.673(1), c = 11.014(2) Å, β = 97.106(2)°, V= 905.0(2) Å3, Z = 2, Dc = 1.969g/cm3, F (000) = 520, R = 0.0474, wR = 0.0925. The compound is cyano-bridged rare earth transition metallic complex. The rare earth ion (Sm34) is seven-coordinated with the conformation of pentagonal bipyramid. The structure of the compound can be described as a square brick stair-like layered structure, which stacks along b axis with hydrogen bond interaction between the layers to form 3D-network structure.

AB - The title compound SmFe(CN)6(DMSO)2·H2O was prepared by the reaction of SmCl3·6H2O with K3Fe(CN)6 in the mixed solvent of H2O/EtOH/DMSO. The crystal of the compound is monoclinic, space group P2/n, a = 7.759(1), b = 10.673(1), c = 11.014(2) Å, β = 97.106(2)°, V= 905.0(2) Å3, Z = 2, Dc = 1.969g/cm3, F (000) = 520, R = 0.0474, wR = 0.0925. The compound is cyano-bridged rare earth transition metallic complex. The rare earth ion (Sm34) is seven-coordinated with the conformation of pentagonal bipyramid. The structure of the compound can be described as a square brick stair-like layered structure, which stacks along b axis with hydrogen bond interaction between the layers to form 3D-network structure.

KW - Crystal structure

KW - Cyano-bridged

KW - Iron

KW - Rare earth

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M3 - Article

AN - SCOPUS:0346512559

SN - 0254-5861

VL - 20

SP - 231

EP - 232

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 3

ER -

Synthesis and Structure of a Novel Cyano-bridged Compound SmFe(CN)₆(DMSO)₂·H₂O

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