Synthesis and self-assembly of 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes

Xuebin Huang; Yunqi Liu; Shuai Wang; Shuqin Zhou; Daoben Zhu

doi:10.1002/1521-3765(20020916)8:18<4179::AID-CHEM4179>3.0.CO;2-L

Synthesis and self-assembly of 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes

Xuebin Huang, Yunqi Liu^*, Shuai Wang, Shuqin Zhou, Daoben Zhu

^*Corresponding author for this work

CAS - Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine (8) and its disulfide (9) have been synthesized and characterized, and their self-assembling behaviors on gold substrates have been studied. Characteristic Q-bands were observed at about 630 nm in the UV/visible spectra of the self-assembling monolayers (SAMs). They were broadened and blue-shifted relative to those observed in solution. Binding energies for S2p have the same values (161.70 eV) and are in accord with those for gold thiolates. The application of the SAMs in organic light-emitting diode was investigated. It shows that the SAM promotes the hole injection process from the anode.

Original language	English
Pages (from-to)	4179-4184
Number of pages	6
Journal	Chemistry - A European Journal
Volume	8
Issue number	18
DOIs	https://doi.org/10.1002/1521-3765(20020916)8:18<4179::AID-CHEM4179>3.0.CO;2-L
Publication status	Published - 16 Sept 2002
Externally published	Yes

Keywords

Hole injection
Organic light-emitting diode
Phthalocyanines
Self-assembly
Synthesis design

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10.1002/1521-3765(20020916)8:18<4179::AID-CHEM4179>3.0.CO;2-L

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title = "Synthesis and self-assembly of 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes",

abstract = "2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine (8) and its disulfide (9) have been synthesized and characterized, and their self-assembling behaviors on gold substrates have been studied. Characteristic Q-bands were observed at about 630 nm in the UV/visible spectra of the self-assembling monolayers (SAMs). They were broadened and blue-shifted relative to those observed in solution. Binding energies for S2p have the same values (161.70 eV) and are in accord with those for gold thiolates. The application of the SAMs in organic light-emitting diode was investigated. It shows that the SAM promotes the hole injection process from the anode.",

keywords = "Hole injection, Organic light-emitting diode, Phthalocyanines, Self-assembly, Synthesis design",

author = "Xuebin Huang and Yunqi Liu and Shuai Wang and Shuqin Zhou and Daoben Zhu",

year = "2002",

month = sep,

day = "16",

doi = "10.1002/1521-3765(20020916)8:18<4179::AID-CHEM4179>3.0.CO;2-L",

language = "English",

volume = "8",

pages = "4179--4184",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "18",

}

Huang, X, Liu, Y, Wang, S, Zhou, S & Zhu, D 2002, 'Synthesis and self-assembly of 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes', Chemistry - A European Journal, vol. 8, no. 18, pp. 4179-4184. https://doi.org/10.1002/1521-3765(20020916)8:18<4179::AID-CHEM4179>3.0.CO;2-L

Synthesis and self-assembly of 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes. / Huang, Xuebin; Liu, Yunqi; Wang, Shuai et al.
In: Chemistry - A European Journal, Vol. 8, No. 18, 16.09.2002, p. 4179-4184.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and self-assembly of 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes

AU - Huang, Xuebin

AU - Liu, Yunqi

AU - Wang, Shuai

AU - Zhou, Shuqin

AU - Zhu, Daoben

PY - 2002/9/16

Y1 - 2002/9/16

N2 - 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine (8) and its disulfide (9) have been synthesized and characterized, and their self-assembling behaviors on gold substrates have been studied. Characteristic Q-bands were observed at about 630 nm in the UV/visible spectra of the self-assembling monolayers (SAMs). They were broadened and blue-shifted relative to those observed in solution. Binding energies for S2p have the same values (161.70 eV) and are in accord with those for gold thiolates. The application of the SAMs in organic light-emitting diode was investigated. It shows that the SAM promotes the hole injection process from the anode.

AB - 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine (8) and its disulfide (9) have been synthesized and characterized, and their self-assembling behaviors on gold substrates have been studied. Characteristic Q-bands were observed at about 630 nm in the UV/visible spectra of the self-assembling monolayers (SAMs). They were broadened and blue-shifted relative to those observed in solution. Binding energies for S2p have the same values (161.70 eV) and are in accord with those for gold thiolates. The application of the SAMs in organic light-emitting diode was investigated. It shows that the SAM promotes the hole injection process from the anode.

KW - Hole injection

KW - Organic light-emitting diode

KW - Phthalocyanines

KW - Self-assembly

KW - Synthesis design

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ER -

Synthesis and self-assembly of 2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes

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Keywords

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