Synthesis and crystal structure of Ag2(admtrz) 2(CF3CO2)2 (admtrz = 4-amino-3, 5-dimethyl-1, 2, 4-triazole)

Jia Cheng Liu; Guo Cong Guo; Hong Wei Ma; Chun Yang; Guo Wei Zhou; Fa Kun Zheng; Shan Huo Lin; Ming Sheng Wang; Jin Shun Huang

Synthesis and crystal structure of Ag₂(admtrz) ₂(CF₃CO₂)₂ (admtrz = 4-amino-3, 5-dimethyl-1, 2, 4-triazole)

Jia Cheng Liu, Guo Cong Guo, Hong Wei Ma, Chun Yang, Guo Wei Zhou, Fa Kun Zheng, Shan Huo Lin, Ming Sheng Wang, Jin Shun Huang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The title compound (Ag₂F₆O₄N ₈C₁₂H₁₆, M_r= 666.07) was synthesized and its crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in orthorhombic, space group Fddd with cell parameters: a = 12.2718(1), b = 23.3229(1), c = 29.1918(1) Å, V = 8355.10(8) Å³, Z = 16, D_c = 2.118 g/cm³, F(000) = 5184 and μ = 1.966 mm^-1. The structure was solved by direct methods and refined by full-matrix least-squares methods. The final R = 0.0624 and Rw = 0.1699 for 1584 observed reflections with I ≥ 2.0σ(I). The molecular structure consists of two trigonal silver atoms bridged by double triazole ligands. The distance between the two silver atoms Ag(1)⋯Ag(1A) is 3.475(2) Å.

Original language	English
Pages (from-to)	371-373
Number of pages	3
Journal	Jiegou Huaxue
Volume	21
Issue number	4
Publication status	Published - 2002
Externally published	Yes

Keywords

4-amino-3, 5-dimethyl-1, 2, 4-triazole
Crystal structure
Silver
Synthesis

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@article{cd14be2a8cf14bd38b93eeac8f0ff953,

title = "Synthesis and crystal structure of Ag2(admtrz) 2(CF3CO2)2 (admtrz = 4-amino-3, 5-dimethyl-1, 2, 4-triazole)",

abstract = "The title compound (Ag2F6O4N 8C12H16, Mr= 666.07) was synthesized and its crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in orthorhombic, space group Fddd with cell parameters: a = 12.2718(1), b = 23.3229(1), c = 29.1918(1) {\AA}, V = 8355.10(8) {\AA}3, Z = 16, Dc = 2.118 g/cm3, F(000) = 5184 and μ = 1.966 mm-1. The structure was solved by direct methods and refined by full-matrix least-squares methods. The final R = 0.0624 and Rw = 0.1699 for 1584 observed reflections with I ≥ 2.0σ(I). The molecular structure consists of two trigonal silver atoms bridged by double triazole ligands. The distance between the two silver atoms Ag(1)⋯Ag(1A) is 3.475(2) {\AA}.",

keywords = "4-amino-3, 5-dimethyl-1, 2, 4-triazole, Crystal structure, Silver, Synthesis",

author = "Liu, {Jia Cheng} and Guo, {Guo Cong} and Ma, {Hong Wei} and Chun Yang and Zhou, {Guo Wei} and Zheng, {Fa Kun} and Lin, {Shan Huo} and Wang, {Ming Sheng} and Huang, {Jin Shun}",

year = "2002",

language = "English",

volume = "21",

pages = "371--373",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "4",

}

TY - JOUR

T1 - Synthesis and crystal structure of Ag2(admtrz) 2(CF3CO2)2 (admtrz = 4-amino-3, 5-dimethyl-1, 2, 4-triazole)

AU - Liu, Jia Cheng

AU - Guo, Guo Cong

AU - Ma, Hong Wei

AU - Yang, Chun

AU - Zhou, Guo Wei

AU - Zheng, Fa Kun

AU - Lin, Shan Huo

AU - Wang, Ming Sheng

AU - Huang, Jin Shun

PY - 2002

Y1 - 2002

N2 - The title compound (Ag2F6O4N 8C12H16, Mr= 666.07) was synthesized and its crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in orthorhombic, space group Fddd with cell parameters: a = 12.2718(1), b = 23.3229(1), c = 29.1918(1) Å, V = 8355.10(8) Å3, Z = 16, Dc = 2.118 g/cm3, F(000) = 5184 and μ = 1.966 mm-1. The structure was solved by direct methods and refined by full-matrix least-squares methods. The final R = 0.0624 and Rw = 0.1699 for 1584 observed reflections with I ≥ 2.0σ(I). The molecular structure consists of two trigonal silver atoms bridged by double triazole ligands. The distance between the two silver atoms Ag(1)⋯Ag(1A) is 3.475(2) Å.

AB - The title compound (Ag2F6O4N 8C12H16, Mr= 666.07) was synthesized and its crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in orthorhombic, space group Fddd with cell parameters: a = 12.2718(1), b = 23.3229(1), c = 29.1918(1) Å, V = 8355.10(8) Å3, Z = 16, Dc = 2.118 g/cm3, F(000) = 5184 and μ = 1.966 mm-1. The structure was solved by direct methods and refined by full-matrix least-squares methods. The final R = 0.0624 and Rw = 0.1699 for 1584 observed reflections with I ≥ 2.0σ(I). The molecular structure consists of two trigonal silver atoms bridged by double triazole ligands. The distance between the two silver atoms Ag(1)⋯Ag(1A) is 3.475(2) Å.

KW - 4-amino-3, 5-dimethyl-1, 2, 4-triazole

KW - Crystal structure

KW - Silver

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=33750342769&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33750342769

SN - 0254-5861

VL - 21

SP - 371

EP - 373

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 4

ER -

Synthesis and crystal structure of Ag₂(admtrz) ₂(CF₃CO₂)₂ (admtrz = 4-amino-3, 5-dimethyl-1, 2, 4-triazole)

Abstract

Keywords

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