Syntheses, structures and characterisation of two CuII polymers with 8-connected topologies based on highly connected SBUs

Jian Zhang; Yao Kang; Jie Zhang; Zhao Ji Li; Ye Yan Qin; Yuan Gen Yao

doi:10.1002/ejic.200500904

Syntheses, structures and characterisation of two Cu^II polymers with 8-connected topologies based on highly connected SBUs

Jian Zhang, Yao Kang, Jie Zhang, Zhao Ji Li, Ye Yan Qin, Yuan Gen Yao^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

Two hydrothermally synthesised 3D metal-coordination polymers, namely [Cu(isonicotinate)(nicotinate)]_n (1), with an 8-connected CsCl topology, and [Cu₂(μ₃-OH)(isonicotinate) ₂(BDC)_0.5]_n (2), with an unusual 8-connected 3⁵.4¹¹.5⁸.6⁴ topology, demonstrate that highly connected SBUs can be employed in the construction of complicated frameworks. The temperature-dependent magnetic susceptibilities for the two complexes were also determined.

Original language	English
Pages (from-to)	2253-2258
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	11
DOIs	https://doi.org/10.1002/ejic.200500904
Publication status	Published - 2 Jun 2006
Externally published	Yes

Keywords

Coordination polymers
Copper
Hydrothermal synthesis
Magnetic properties
N ligands

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10.1002/ejic.200500904

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title = "Syntheses, structures and characterisation of two CuII polymers with 8-connected topologies based on highly connected SBUs",

abstract = "Two hydrothermally synthesised 3D metal-coordination polymers, namely [Cu(isonicotinate)(nicotinate)]n (1), with an 8-connected CsCl topology, and [Cu2(μ3-OH)(isonicotinate) 2(BDC)0.5]n (2), with an unusual 8-connected 35.411.58.64 topology, demonstrate that highly connected SBUs can be employed in the construction of complicated frameworks. The temperature-dependent magnetic susceptibilities for the two complexes were also determined.",

keywords = "Coordination polymers, Copper, Hydrothermal synthesis, Magnetic properties, N ligands",

author = "Jian Zhang and Yao Kang and Jie Zhang and Li, {Zhao Ji} and Qin, {Ye Yan} and Yao, {Yuan Gen}",

year = "2006",

month = jun,

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doi = "10.1002/ejic.200500904",

language = "English",

pages = "2253--2258",

journal = "European Journal of Inorganic Chemistry",

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T1 - Syntheses, structures and characterisation of two CuII polymers with 8-connected topologies based on highly connected SBUs

AU - Zhang, Jian

AU - Kang, Yao

AU - Zhang, Jie

AU - Li, Zhao Ji

AU - Qin, Ye Yan

AU - Yao, Yuan Gen

PY - 2006/6/2

Y1 - 2006/6/2

N2 - Two hydrothermally synthesised 3D metal-coordination polymers, namely [Cu(isonicotinate)(nicotinate)]n (1), with an 8-connected CsCl topology, and [Cu2(μ3-OH)(isonicotinate) 2(BDC)0.5]n (2), with an unusual 8-connected 35.411.58.64 topology, demonstrate that highly connected SBUs can be employed in the construction of complicated frameworks. The temperature-dependent magnetic susceptibilities for the two complexes were also determined.

AB - Two hydrothermally synthesised 3D metal-coordination polymers, namely [Cu(isonicotinate)(nicotinate)]n (1), with an 8-connected CsCl topology, and [Cu2(μ3-OH)(isonicotinate) 2(BDC)0.5]n (2), with an unusual 8-connected 35.411.58.64 topology, demonstrate that highly connected SBUs can be employed in the construction of complicated frameworks. The temperature-dependent magnetic susceptibilities for the two complexes were also determined.

KW - Coordination polymers

KW - Copper

KW - Hydrothermal synthesis

KW - Magnetic properties

KW - N ligands

UR - http://www.scopus.com/inward/record.url?scp=33745161407&partnerID=8YFLogxK

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DO - 10.1002/ejic.200500904

M3 - Article

AN - SCOPUS:33745161407

SN - 1434-1948

SP - 2253

EP - 2258

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 11

ER -

Syntheses, structures and characterisation of two Cu^II polymers with 8-connected topologies based on highly connected SBUs

Abstract

Keywords

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