Syntheses and structural characterizations of two compounds containing similar backbone anion {V10}

Xiao Ping Zhan; Can Zhong Lu; Wen Bin Yang; Hong Wei Ma; Chuan De Wu; Quan Zheng Zhang; Xiao Yu Jiang

Syntheses and structural characterizations of two compounds containing similar backbone anion {V₁₀}

Xiao Ping Zhan^*, Can Zhong Lu, Wen Bin Yang, Hong Wei Ma, Chuan De Wu, Quan Zheng Zhang, Xiao Yu Jiang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Two compounds with similar anion backbone, [Na₂(H ₂O)₁₀(NH₄)₄][V₁₀O ₂₈] (1) and [Na₂(H₂O)₁₀(NH ₄)₄] [V₉MoO₂₈] (2), are discribed. The anion of 1 is of decavanadate with normal structure, while the anion of 2 has a molybdenum atom mixing with four vanadinum atoms at certain positions in the similar backbone of the decanucleus structure. Crystal data for H ₃₆N₄O₃₈Na₂V₁₀ (1): triclinic, space group P1̄, a = 0.86024(4) nm, b = 1.04561(5) nm, c = 1.12828(4) nm, α = 68.833(1)°, β = 87.158(1)°, γ = 67.065(1)°, V = 0.86665(7) nm³, Z = 1, M_r = 1255.71, D_c = 2.406g·cm^-3, F(000) = 620, μ(Mo Kα) = 2.719mm^-1. Crystal data for H₃₆N₄O ₃₈Na₂V₉Mo (2): triclinic, space group P1̄, a = 0.86511(3) nm, b = 1.04549(5) nm, c = 1.12446(5) nm, α = 69.071(1)°, β = 87.145(1)°, γ = 66.982(1)°, V = 0.86951(6) nm³, Z = 1, M_r = 1300.71, D_c = 2.484g·cm^-3, F(000) = 639, μ(Mo Kα) = 2.802mm ^-1. CSD: 1, 413132, 2, 413133.

Original language	English
Pages (from-to)	831-836
Number of pages	6
Journal	Chinese Journal of Inorganic Chemistry
Volume	19
Issue number	8
Publication status	Published - 1 Aug 2003
Externally published	Yes

Keywords

Decavanadate
Hydrothermal synthesis
Polyoxometalatic chemistry

Cite this

@article{7c58251a94ac4746817cad9dc1d77930,

title = "Syntheses and structural characterizations of two compounds containing similar backbone anion {V10}",

abstract = "Two compounds with similar anion backbone, [Na2(H 2O)10(NH4)4][V10O 28] (1) and [Na2(H2O)10(NH 4)4] [V9MoO28] (2), are discribed. The anion of 1 is of decavanadate with normal structure, while the anion of 2 has a molybdenum atom mixing with four vanadinum atoms at certain positions in the similar backbone of the decanucleus structure. Crystal data for H 36N4O38Na2V10 (1): triclinic, space group P{\=1}, a = 0.86024(4) nm, b = 1.04561(5) nm, c = 1.12828(4) nm, α = 68.833(1)°, β = 87.158(1)°, γ = 67.065(1)°, V = 0.86665(7) nm3, Z = 1, Mr = 1255.71, Dc = 2.406g·cm-3, F(000) = 620, μ(Mo Kα) = 2.719mm-1. Crystal data for H36N4O 38Na2V9Mo (2): triclinic, space group P{\=1}, a = 0.86511(3) nm, b = 1.04549(5) nm, c = 1.12446(5) nm, α = 69.071(1)°, β = 87.145(1)°, γ = 66.982(1)°, V = 0.86951(6) nm3, Z = 1, Mr = 1300.71, Dc = 2.484g·cm-3, F(000) = 639, μ(Mo Kα) = 2.802mm -1. CSD: 1, 413132, 2, 413133.",

keywords = "Decavanadate, Hydrothermal synthesis, Polyoxometalatic chemistry",

author = "Zhan, {Xiao Ping} and Lu, {Can Zhong} and Yang, {Wen Bin} and Ma, {Hong Wei} and Wu, {Chuan De} and Zhang, {Quan Zheng} and Jiang, {Xiao Yu}",

year = "2003",

month = aug,

day = "1",

language = "English",

volume = "19",

pages = "831--836",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "8",

}

TY - JOUR

T1 - Syntheses and structural characterizations of two compounds containing similar backbone anion {V10}

AU - Zhan, Xiao Ping

AU - Lu, Can Zhong

AU - Yang, Wen Bin

AU - Ma, Hong Wei

AU - Wu, Chuan De

AU - Zhang, Quan Zheng

AU - Jiang, Xiao Yu

PY - 2003/8/1

Y1 - 2003/8/1

N2 - Two compounds with similar anion backbone, [Na2(H 2O)10(NH4)4][V10O 28] (1) and [Na2(H2O)10(NH 4)4] [V9MoO28] (2), are discribed. The anion of 1 is of decavanadate with normal structure, while the anion of 2 has a molybdenum atom mixing with four vanadinum atoms at certain positions in the similar backbone of the decanucleus structure. Crystal data for H 36N4O38Na2V10 (1): triclinic, space group P1̄, a = 0.86024(4) nm, b = 1.04561(5) nm, c = 1.12828(4) nm, α = 68.833(1)°, β = 87.158(1)°, γ = 67.065(1)°, V = 0.86665(7) nm3, Z = 1, Mr = 1255.71, Dc = 2.406g·cm-3, F(000) = 620, μ(Mo Kα) = 2.719mm-1. Crystal data for H36N4O 38Na2V9Mo (2): triclinic, space group P1̄, a = 0.86511(3) nm, b = 1.04549(5) nm, c = 1.12446(5) nm, α = 69.071(1)°, β = 87.145(1)°, γ = 66.982(1)°, V = 0.86951(6) nm3, Z = 1, Mr = 1300.71, Dc = 2.484g·cm-3, F(000) = 639, μ(Mo Kα) = 2.802mm -1. CSD: 1, 413132, 2, 413133.

AB - Two compounds with similar anion backbone, [Na2(H 2O)10(NH4)4][V10O 28] (1) and [Na2(H2O)10(NH 4)4] [V9MoO28] (2), are discribed. The anion of 1 is of decavanadate with normal structure, while the anion of 2 has a molybdenum atom mixing with four vanadinum atoms at certain positions in the similar backbone of the decanucleus structure. Crystal data for H 36N4O38Na2V10 (1): triclinic, space group P1̄, a = 0.86024(4) nm, b = 1.04561(5) nm, c = 1.12828(4) nm, α = 68.833(1)°, β = 87.158(1)°, γ = 67.065(1)°, V = 0.86665(7) nm3, Z = 1, Mr = 1255.71, Dc = 2.406g·cm-3, F(000) = 620, μ(Mo Kα) = 2.719mm-1. Crystal data for H36N4O 38Na2V9Mo (2): triclinic, space group P1̄, a = 0.86511(3) nm, b = 1.04549(5) nm, c = 1.12446(5) nm, α = 69.071(1)°, β = 87.145(1)°, γ = 66.982(1)°, V = 0.86951(6) nm3, Z = 1, Mr = 1300.71, Dc = 2.484g·cm-3, F(000) = 639, μ(Mo Kα) = 2.802mm -1. CSD: 1, 413132, 2, 413133.

KW - Decavanadate

KW - Hydrothermal synthesis

KW - Polyoxometalatic chemistry

UR - http://www.scopus.com/inward/record.url?scp=0141517559&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0141517559

SN - 1001-4861

VL - 19

SP - 831

EP - 836

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 8

ER -

Syntheses and structural characterizations of two compounds containing similar backbone anion {V₁₀}

Abstract

Keywords

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