Study on performance of transition metal-doped catalysts for DeNOx at low-temperature

Jin Shuo Qiao, Cui Ya Zhang, Xiao Ju Yin, Ke Ning Sun

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Citation (Scopus)

Abstract

Mn-Ce based catalysts doped with transition metal were synthesized via a sol-gel method for low-temperature Selective catalytic reduction DeNOx. NOx conversion of these catalysts was evaluated under 100 °C -300 °C. H2-Temperature Programmed Reduction was used to investigate the reduction capability effect on NOx conversion. On this basis, sulfur resistance of catalysts was analyzed and Fourier Transform Infrared (FI-IR) spectra were used to discuss sulfur poisoning mechanism of catalysts. The results indicated that NOx conversion of catalysts was Mn-Ce-W0.03 ≈ Mn-Ce-Y0.03 > Mn-Ce-Zr0.03 > Mn-Ce >Mn-Ce-La0.03 > Mn-Ce-Pr0.03.W, Zr, Y elements was doped to improve catalytic activity at low-temperature and enhance anti-sulfur ability of catalysts. Especially, W element can restrain sulfate formation and reduce the channel blocking of the catalyst and Mn-Ce-W0.03 catalyst displays optimal performance of resistance to sulfur poisoning.

Original languageEnglish
Title of host publication8th China National Conference on Functional Materials and Applications
Pages612-618
Number of pages7
DOIs
Publication statusPublished - 2014
Externally publishedYes
Event8th China National Conference on Functional Materials and Applications, NCFMA 2013 - Harbin, China
Duration: 23 Aug 201326 Aug 2013

Publication series

NameAdvanced Materials Research
Volume873
ISSN (Print)1022-6680

Conference

Conference8th China National Conference on Functional Materials and Applications, NCFMA 2013
Country/TerritoryChina
CityHarbin
Period23/08/1326/08/13

Keywords

  • Low-temperature
  • Mn-based catalyst
  • Resistance
  • Selective catalytic reduction DeNOx
  • Sulfur

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