Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

Ya Nan Dong; Jin Peng Xue; Meng Yu; Jun Tao

doi:10.1016/j.inoche.2022.109475

Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

Ya Nan Dong, Jin Peng Xue, Meng Yu^*, Jun Tao

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)₂] in methanol, i.e. trans-[Fe₂(pyrtrz)₅(NCS)₄]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.

Original language	English
Article number	109475
Journal	Inorganic Chemistry Communications
Volume	140
DOIs	https://doi.org/10.1016/j.inoche.2022.109475
Publication status	Published - Jun 2022

Keywords

4-substituted triazole ligand
Dinuclear complex
Polymorphism
Spin crossover

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10.1016/j.inoche.2022.109475

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title = "Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure",

abstract = "A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)2] in methanol, i.e. trans-[Fe2(pyrtrz)5(NCS)4]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.",

keywords = "4-substituted triazole ligand, Dinuclear complex, Polymorphism, Spin crossover",

author = "Dong, {Ya Nan} and Xue, {Jin Peng} and Meng Yu and Jun Tao",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2022",

month = jun,

doi = "10.1016/j.inoche.2022.109475",

language = "English",

volume = "140",

journal = "Inorganic Chemistry Communications",

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TY - JOUR

T1 - Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

AU - Dong, Ya Nan

AU - Xue, Jin Peng

AU - Yu, Meng

AU - Tao, Jun

PY - 2022/6

Y1 - 2022/6

N2 - A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)2] in methanol, i.e. trans-[Fe2(pyrtrz)5(NCS)4]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.

AB - A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)2] in methanol, i.e. trans-[Fe2(pyrtrz)5(NCS)4]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.

KW - 4-substituted triazole ligand

KW - Dinuclear complex

KW - Polymorphism

KW - Spin crossover

UR - http://www.scopus.com/inward/record.url?scp=85129263587&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2022.109475

DO - 10.1016/j.inoche.2022.109475

M3 - Article

AN - SCOPUS:85129263587

SN - 1387-7003

VL - 140

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 109475

ER -

Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

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Keywords

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