Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

Ni Zhen; Jing Dong; Zhengguo Lin; Xiaoxia Li; Yingnan Chi; Changwen Hu

doi:10.1039/d0cc06277d

Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

Ni Zhen, Jing Dong, Zhengguo Lin, Xiaoxia Li, Yingnan Chi^*, Changwen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.

Original language	English
Pages (from-to)	13967-13970
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	90
DOIs	https://doi.org/10.1039/d0cc06277d
Publication status	Published - 21 Nov 2020

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abstract = "We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.",

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T1 - Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

AU - Zhen, Ni

AU - Dong, Jing

AU - Lin, Zhengguo

AU - Li, Xiaoxia

AU - Chi, Yingnan

AU - Hu, Changwen

PY - 2020/11/21

Y1 - 2020/11/21

N2 - We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.

AB - We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.

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U2 - 10.1039/d0cc06277d

DO - 10.1039/d0cc06277d

M3 - Article

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SN - 1359-7345

VL - 56

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EP - 13970

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

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