Self-assembly and host-guest interaction of metallomacrocycles using fluorescent dipyrazole linker with dimetallic clips

Guo Hong Ning; Liao Yuan Yao; Li Xia Liu; Ting Zheng Xie; Yi Zhi Li; Yu Qin; Yuan Jiang Pan; Shu Yan Yu

doi:10.1021/ic100724r

Self-assembly and host-guest interaction of metallomacrocycles using fluorescent dipyrazole linker with dimetallic clips

Guo Hong Ning, Liao Yuan Yao, Li Xia Liu, Ting Zheng Xie, Yi Zhi Li, Yu Qin^*, Yuan Jiang Pan, Shu Yan Yu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

By employing diimine ligands coordinated dimetallic clips ([(bpy) ₂Pd₂(NO₃)₂](NO₃) ₂ or [(phen)₂Pd₂(NO₃) ₂](NO₃)₂, where bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline) as the corner and anthracene-, naphthalene-, and benzene-based dipyrazolate dianions as the linker, a series of positively charged metallomacrocycles ([M₄L₂]⁴⁺ or [M ₈L₄]⁸⁺) have been synthesized through a directed self-assembly method in aqueous solution. Every macrocycle has a cavity to bind solvent molecules or anions. The structures were characterized by elemental analysis, ¹H and ¹³C NMR, electrospray ionization mass spectrometry, and single crystal X-ray diffraction analysis for compound 1 4PF₆ (1 = {[(bpy)Pd]₄L¹ ₂}⁴⁺), 3 4PF₆ ·8CH₃CN· H₂O (3 = {[(bpy)Pd]₄L²₂} ⁴⁺), and 7 4PF₆·6H₂O (7 = {[(bpy)Pd]₄L⁵₂}⁴⁺). The 1:1 host-guest complexation for anthracene-based dipyrazolate-bridged macrocycles with aromatic guests was investigated via UV-vis and fluorescent titration.

Original language	English
Pages (from-to)	7783-7792
Number of pages	10
Journal	Inorganic Chemistry
Volume	49
Issue number	17
DOIs	https://doi.org/10.1021/ic100724r
Publication status	Published - 6 Sept 2010
Externally published	Yes

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@article{9dca39bdce044a84a745993eb3ee8013,

title = "Self-assembly and host-guest interaction of metallomacrocycles using fluorescent dipyrazole linker with dimetallic clips",

abstract = "By employing diimine ligands coordinated dimetallic clips ([(bpy) 2Pd2(NO3)2](NO3) 2 or [(phen)2Pd2(NO3) 2](NO3)2, where bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline) as the corner and anthracene-, naphthalene-, and benzene-based dipyrazolate dianions as the linker, a series of positively charged metallomacrocycles ([M4L2]4+ or [M 8L4]8+) have been synthesized through a directed self-assembly method in aqueous solution. Every macrocycle has a cavity to bind solvent molecules or anions. The structures were characterized by elemental analysis, 1H and 13C NMR, electrospray ionization mass spectrometry, and single crystal X-ray diffraction analysis for compound 1 4PF6 (1 = {[(bpy)Pd]4L1 2}4+), 3 4PF6 ·8CH3CN· H2O (3 = {[(bpy)Pd]4L22} 4+), and 7 4PF6·6H2O (7 = {[(bpy)Pd]4L52}4+). The 1:1 host-guest complexation for anthracene-based dipyrazolate-bridged macrocycles with aromatic guests was investigated via UV-vis and fluorescent titration.",

author = "Ning, {Guo Hong} and Yao, {Liao Yuan} and Liu, {Li Xia} and Xie, {Ting Zheng} and Li, {Yi Zhi} and Yu Qin and Pan, {Yuan Jiang} and Yu, {Shu Yan}",

year = "2010",

month = sep,

day = "6",

doi = "10.1021/ic100724r",

language = "English",

volume = "49",

pages = "7783--7792",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "17",

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T1 - Self-assembly and host-guest interaction of metallomacrocycles using fluorescent dipyrazole linker with dimetallic clips

AU - Ning, Guo Hong

AU - Yao, Liao Yuan

AU - Liu, Li Xia

AU - Xie, Ting Zheng

AU - Li, Yi Zhi

AU - Qin, Yu

AU - Pan, Yuan Jiang

AU - Yu, Shu Yan

PY - 2010/9/6

Y1 - 2010/9/6

N2 - By employing diimine ligands coordinated dimetallic clips ([(bpy) 2Pd2(NO3)2](NO3) 2 or [(phen)2Pd2(NO3) 2](NO3)2, where bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline) as the corner and anthracene-, naphthalene-, and benzene-based dipyrazolate dianions as the linker, a series of positively charged metallomacrocycles ([M4L2]4+ or [M 8L4]8+) have been synthesized through a directed self-assembly method in aqueous solution. Every macrocycle has a cavity to bind solvent molecules or anions. The structures were characterized by elemental analysis, 1H and 13C NMR, electrospray ionization mass spectrometry, and single crystal X-ray diffraction analysis for compound 1 4PF6 (1 = {[(bpy)Pd]4L1 2}4+), 3 4PF6 ·8CH3CN· H2O (3 = {[(bpy)Pd]4L22} 4+), and 7 4PF6·6H2O (7 = {[(bpy)Pd]4L52}4+). The 1:1 host-guest complexation for anthracene-based dipyrazolate-bridged macrocycles with aromatic guests was investigated via UV-vis and fluorescent titration.

AB - By employing diimine ligands coordinated dimetallic clips ([(bpy) 2Pd2(NO3)2](NO3) 2 or [(phen)2Pd2(NO3) 2](NO3)2, where bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline) as the corner and anthracene-, naphthalene-, and benzene-based dipyrazolate dianions as the linker, a series of positively charged metallomacrocycles ([M4L2]4+ or [M 8L4]8+) have been synthesized through a directed self-assembly method in aqueous solution. Every macrocycle has a cavity to bind solvent molecules or anions. The structures were characterized by elemental analysis, 1H and 13C NMR, electrospray ionization mass spectrometry, and single crystal X-ray diffraction analysis for compound 1 4PF6 (1 = {[(bpy)Pd]4L1 2}4+), 3 4PF6 ·8CH3CN· H2O (3 = {[(bpy)Pd]4L22} 4+), and 7 4PF6·6H2O (7 = {[(bpy)Pd]4L52}4+). The 1:1 host-guest complexation for anthracene-based dipyrazolate-bridged macrocycles with aromatic guests was investigated via UV-vis and fluorescent titration.

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U2 - 10.1021/ic100724r

DO - 10.1021/ic100724r

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SN - 0020-1669

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EP - 7792

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Self-assembly and host-guest interaction of metallomacrocycles using fluorescent dipyrazole linker with dimetallic clips

Abstract

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