Selective on/off switching at room temperature of a magnetic bistable (Fe2Co2) complex with single crystal-to-single crystal transformation via intramolecular electron transfer

Li Cao; Jun Tao; Qian Gao; Tao Liu; Zhengcai Xia; Dongfeng Li

doi:10.1039/c3cc48116f

Selective on/off switching at room temperature of a magnetic bistable (Fe₂Co₂) complex with single crystal-to-single crystal transformation via intramolecular electron transfer

Li Cao, Jun Tao, Qian Gao, Tao Liu, Zhengcai Xia, Dongfeng Li^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

A cyano-bridged (Fe₂Co₂) complex shows reversible single crystal-to-single crystal transformation between diamagnetic and paramagnetic states switched specifically by losing and absorbing methanol at room temperature in the solid state. And the solvent loss form presents temperature- and pressure-induced intramolecular electron transfer behaviour.

Original language	English
Pages (from-to)	1665-1667
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	14
DOIs	https://doi.org/10.1039/c3cc48116f
Publication status	Published - 21 Jan 2014
Externally published	Yes

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title = "Selective on/off switching at room temperature of a magnetic bistable (Fe2Co2) complex with single crystal-to-single crystal transformation via intramolecular electron transfer",

abstract = "A cyano-bridged (Fe2Co2) complex shows reversible single crystal-to-single crystal transformation between diamagnetic and paramagnetic states switched specifically by losing and absorbing methanol at room temperature in the solid state. And the solvent loss form presents temperature- and pressure-induced intramolecular electron transfer behaviour.",

author = "Li Cao and Jun Tao and Qian Gao and Tao Liu and Zhengcai Xia and Dongfeng Li",

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AU - Cao, Li

AU - Tao, Jun

AU - Gao, Qian

AU - Liu, Tao

AU - Xia, Zhengcai

AU - Li, Dongfeng

PY - 2014/1/21

Y1 - 2014/1/21

N2 - A cyano-bridged (Fe2Co2) complex shows reversible single crystal-to-single crystal transformation between diamagnetic and paramagnetic states switched specifically by losing and absorbing methanol at room temperature in the solid state. And the solvent loss form presents temperature- and pressure-induced intramolecular electron transfer behaviour.

AB - A cyano-bridged (Fe2Co2) complex shows reversible single crystal-to-single crystal transformation between diamagnetic and paramagnetic states switched specifically by losing and absorbing methanol at room temperature in the solid state. And the solvent loss form presents temperature- and pressure-induced intramolecular electron transfer behaviour.

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U2 - 10.1039/c3cc48116f

DO - 10.1039/c3cc48116f

M3 - Article

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SN - 1359-7345

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SP - 1665

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JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Selective on/off switching at room temperature of a magnetic bistable (Fe₂Co₂) complex with single crystal-to-single crystal transformation via intramolecular electron transfer

Abstract

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