Abstract
Frustrated, but not frustrating: Frustrated Lewis pairs (FLPs) can undergo selective 1,4-addition reactions with conjugated ynones (see scheme). Upon FLP dihydrogen activation selective hydrogenation of the carbon-carbon triple bond can be achieved, in one case even catalytically.
Original language | English |
---|---|
Pages (from-to) | 7183-7186 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 50 |
Issue number | 31 |
DOIs | |
Publication status | Published - 25 Jul 2011 |
Externally published | Yes |
Keywords
- 1,4-additions
- allenes
- frustrated Lewis pairs
- hydrogenations
- ynones