Preparation of ethylene chlorotrifluoroethylene co-polymer membranes via thermally induced phase separation

Bo Zhou, Ya Kai Lin, Wen Zhong Ma, Yuan Hui Tang, Ye Tian, Xiao Lin Wang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Microporous ethylene chlorotrifluoroethylene co-polymer(ECTFE) membrane was prepared via thermally induced phase separation(TIPS) method. By an analysis of interaction parameter, compatibility of ECTFE/diluent systems and the membrane cross-section morphologies, the liquid-liquid phase separation was found during the TIPS process when diethyl phthalate(DEP) was chosen as a diluent. The thermodynamic phase diagram confirms that a large liquid-liquid phase separation region for the ECTFE/DEP system was observed. The monotectic point of this system appeared at a high polymer concentration which was approximately up to 55%. Moreover, the effects of the cooling temperature and coarsening time on membrane structure, porosity, and tensile strength were also investigated. The results showed that a faster cooling rate and shorter coarsening time at 458 K led to membranes with smaller pore size.

Original languageEnglish
Pages (from-to)2585-2590
Number of pages6
JournalKao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume33
Issue number11
DOIs
Publication statusPublished - Nov 2012
Externally publishedYes

Keywords

  • Diethyl phthalate
  • Ethylene chlorotrifluoroethylene co-polymer
  • Microporous membrane
  • Thermally induced phase separation

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