Preparation of 1,1,1,3,3-pentafluoropropane (HFC-245fa) by using a SbF5-attached catalyst

Heng Dao Quan; Hui E. Yang; Masanori Tamura; Akira Sekiya

doi:10.1016/j.jfluchem.2006.12.004

Preparation of 1,1,1,3,3-pentafluoropropane (HFC-245fa) by using a SbF5-attached catalyst

Heng Dao Quan^*, Hui E. Yang, Masanori Tamura, Akira Sekiya

^*Corresponding author for this work

National Institute of Advanced Industrial Science and Technology

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

In this report, a simple process for preparing HFC-245fa through the reaction of 1,1,1,3,3-pentachloropropane (PCP) and anhydrous HF via two-step vapor-phase catalytic fluorination is described. The antimony pentafluoride catalyst was supported on inert porous materials to improve the catalytic activity. The resulting process catalyst not only exhibited high catalytic activity and excellent thermo-stability, but also improved the performance of SbF₅, in terms of hygroscopicity and corrosion.

Original language	English
Pages (from-to)	190-195
Number of pages	6
Journal	Journal of Fluorine Chemistry
Volume	128
Issue number	3
DOIs	https://doi.org/10.1016/j.jfluchem.2006.12.004
Publication status	Published - Mar 2007
Externally published	Yes

Keywords

1,1,1,3,3-Pentachloropropane
1,1,1,3,3-Pentafluoropropane (HFC-245fa)
1-Chloro-3,3,3-trifluoropropene
Fluorinated catalyst
Vapor-phase catalytic fluorination

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10.1016/j.jfluchem.2006.12.004

Cite this

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title = "Preparation of 1,1,1,3,3-pentafluoropropane (HFC-245fa) by using a SbF5-attached catalyst",

abstract = "In this report, a simple process for preparing HFC-245fa through the reaction of 1,1,1,3,3-pentachloropropane (PCP) and anhydrous HF via two-step vapor-phase catalytic fluorination is described. The antimony pentafluoride catalyst was supported on inert porous materials to improve the catalytic activity. The resulting process catalyst not only exhibited high catalytic activity and excellent thermo-stability, but also improved the performance of SbF5, in terms of hygroscopicity and corrosion.",

keywords = "1,1,1,3,3-Pentachloropropane, 1,1,1,3,3-Pentafluoropropane (HFC-245fa), 1-Chloro-3,3,3-trifluoropropene, Fluorinated catalyst, Vapor-phase catalytic fluorination",

author = "Quan, {Heng Dao} and Yang, {Hui E.} and Masanori Tamura and Akira Sekiya",

year = "2007",

month = mar,

doi = "10.1016/j.jfluchem.2006.12.004",

language = "English",

volume = "128",

pages = "190--195",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Preparation of 1,1,1,3,3-pentafluoropropane (HFC-245fa) by using a SbF5-attached catalyst

AU - Quan, Heng Dao

AU - Yang, Hui E.

AU - Tamura, Masanori

AU - Sekiya, Akira

PY - 2007/3

Y1 - 2007/3

N2 - In this report, a simple process for preparing HFC-245fa through the reaction of 1,1,1,3,3-pentachloropropane (PCP) and anhydrous HF via two-step vapor-phase catalytic fluorination is described. The antimony pentafluoride catalyst was supported on inert porous materials to improve the catalytic activity. The resulting process catalyst not only exhibited high catalytic activity and excellent thermo-stability, but also improved the performance of SbF5, in terms of hygroscopicity and corrosion.

AB - In this report, a simple process for preparing HFC-245fa through the reaction of 1,1,1,3,3-pentachloropropane (PCP) and anhydrous HF via two-step vapor-phase catalytic fluorination is described. The antimony pentafluoride catalyst was supported on inert porous materials to improve the catalytic activity. The resulting process catalyst not only exhibited high catalytic activity and excellent thermo-stability, but also improved the performance of SbF5, in terms of hygroscopicity and corrosion.

KW - 1,1,1,3,3-Pentachloropropane

KW - 1,1,1,3,3-Pentafluoropropane (HFC-245fa)

KW - 1-Chloro-3,3,3-trifluoropropene

KW - Fluorinated catalyst

KW - Vapor-phase catalytic fluorination

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U2 - 10.1016/j.jfluchem.2006.12.004

DO - 10.1016/j.jfluchem.2006.12.004

M3 - Article

AN - SCOPUS:33846838492

SN - 0022-1139

VL - 128

SP - 190

EP - 195

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 3

ER -

Preparation of 1,1,1,3,3-pentafluoropropane (HFC-245fa) by using a SbF5-attached catalyst

Abstract

Keywords

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