Poly[nickel(II)-μ-4,4′-bipyridine-′-terephthalato]

Shi Yao Yang; La Sheng Long; Jun Tao; Rong Bin Huang; Lan Sun Zheng; Seik Weng Ng

doi:10.1107/S1600536803012704

Poly[nickel(II)-μ-4,4′-bipyridine-′-terephthalato]

Shi Yao Yang, La Sheng Long, Jun Tao, Rong Bin Huang, Lan Sun Zheng, Seik Weng Ng^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

4,4′-Bipyridine(terephthalato)nickel(II), [Ni(C₈H ₄O₄)(C₁₀H₈-N₂)], exists as poly[μ₂-terephthalato-μ₄-terephthalato-bis- [(μ₂-4,4′-bipyridine)nickel(II)]]. Two independent terephthalato groups both occupy positions of 2/m symmetry; one of these groups acts as a μ₄ bridge and coordinates four different Ni atoms, one with each of its O atoms. The other one acts as a μ₂-bridge and serves as a bidentate chelate for two neighboring metal atoms. The Ni atom lies in a special position of m site symmetry.

Original language	English
Pages (from-to)	m454-m455
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	7
DOIs	https://doi.org/10.1107/S1600536803012704
Publication status	Published - Jul 2003
Externally published	Yes

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Yang, S. Y., Long, L. S., Tao, J., Huang, R. B., Zheng, L. S., & Ng, S. W. (2003). Poly[nickel(II)-μ-4,4′-bipyridine-′-terephthalato]. Acta Crystallographica Section E: Structure Reports Online, 59(7), m454-m455. https://doi.org/10.1107/S1600536803012704

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title = "Poly[nickel(II)-μ-4,4′-bipyridine-′-terephthalato]",

abstract = "4,4′-Bipyridine(terephthalato)nickel(II), [Ni(C8H 4O4)(C10H8-N2)], exists as poly[μ2-terephthalato-μ4-terephthalato-bis- [(μ2-4,4′-bipyridine)nickel(II)]]. Two independent terephthalato groups both occupy positions of 2/m symmetry; one of these groups acts as a μ4 bridge and coordinates four different Ni atoms, one with each of its O atoms. The other one acts as a μ2-bridge and serves as a bidentate chelate for two neighboring metal atoms. The Ni atom lies in a special position of m site symmetry.",

author = "Yang, {Shi Yao} and Long, {La Sheng} and Jun Tao and Huang, {Rong Bin} and Zheng, {Lan Sun} and Ng, {Seik Weng}",

year = "2003",

month = jul,

doi = "10.1107/S1600536803012704",

language = "English",

volume = "59",

pages = "m454--m455",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

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TY - JOUR

T1 - Poly[nickel(II)-μ-4,4′-bipyridine-′-terephthalato]

AU - Yang, Shi Yao

AU - Long, La Sheng

AU - Tao, Jun

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

AU - Ng, Seik Weng

PY - 2003/7

Y1 - 2003/7

N2 - 4,4′-Bipyridine(terephthalato)nickel(II), [Ni(C8H 4O4)(C10H8-N2)], exists as poly[μ2-terephthalato-μ4-terephthalato-bis- [(μ2-4,4′-bipyridine)nickel(II)]]. Two independent terephthalato groups both occupy positions of 2/m symmetry; one of these groups acts as a μ4 bridge and coordinates four different Ni atoms, one with each of its O atoms. The other one acts as a μ2-bridge and serves as a bidentate chelate for two neighboring metal atoms. The Ni atom lies in a special position of m site symmetry.

AB - 4,4′-Bipyridine(terephthalato)nickel(II), [Ni(C8H 4O4)(C10H8-N2)], exists as poly[μ2-terephthalato-μ4-terephthalato-bis- [(μ2-4,4′-bipyridine)nickel(II)]]. Two independent terephthalato groups both occupy positions of 2/m symmetry; one of these groups acts as a μ4 bridge and coordinates four different Ni atoms, one with each of its O atoms. The other one acts as a μ2-bridge and serves as a bidentate chelate for two neighboring metal atoms. The Ni atom lies in a special position of m site symmetry.

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U2 - 10.1107/S1600536803012704

DO - 10.1107/S1600536803012704

M3 - Article

AN - SCOPUS:18444363055

SN - 1600-5368

VL - 59

SP - m454-m455

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Poly[nickel(II)-μ-4,4′-bipyridine-′-terephthalato]

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