Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

Jun Tao; Xin Yin; Rong Bin Huang; Lan Sun Zheng; Seik Weng Ng

doi:10.1107/S1600536803015289

Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

Jun Tao, Xin Yin, Rong Bin Huang, Lan Sun Zheng, Seik Weng Ng^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The title crystal structure, (Na₂[Cd₂(C ₁₂H₁₀N₂)(C₈H₃O ₇S)₂]·-6H₂O)_n, contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.

Original language	English
Pages (from-to)	m611-m613
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	8
DOIs	https://doi.org/10.1107/S1600536803015289
Publication status	Published - Aug 2003
Externally published	Yes

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title = "Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate",

abstract = "The title crystal structure, (Na2[Cd2(C 12H10N2)(C8H3O 7S)2]·-6H2O)n, contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.",

author = "Jun Tao and Xin Yin and Huang, {Rong Bin} and Zheng, {Lan Sun} and Ng, {Seik Weng}",

year = "2003",

month = aug,

doi = "10.1107/S1600536803015289",

language = "English",

volume = "59",

pages = "m611--m613",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

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T1 - Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

AU - Tao, Jun

AU - Yin, Xin

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

AU - Ng, Seik Weng

PY - 2003/8

Y1 - 2003/8

N2 - The title crystal structure, (Na2[Cd2(C 12H10N2)(C8H3O 7S)2]·-6H2O)n, contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.

AB - The title crystal structure, (Na2[Cd2(C 12H10N2)(C8H3O 7S)2]·-6H2O)n, contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.

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DO - 10.1107/S1600536803015289

M3 - Article

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SN - 1600-5368

VL - 59

SP - m611-m613

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

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