Octavinylsilsesquioxane-based luminescent nanoporous inorganic-organic hybrid polymers constructed by the Heck coupling reaction

Libo Sun; Zhiqiang Liang; Jihong Yu

doi:10.1039/c4py01284d

Octavinylsilsesquioxane-based luminescent nanoporous inorganic-organic hybrid polymers constructed by the Heck coupling reaction

Libo Sun, Zhiqiang Liang^*, Jihong Yu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

The Heck coupling reaction of vinyl-terminated double four-ring siloxane cages (octavinylsilsesquioxane) with aromatic bromide monomers (4,4′-dibromobiphenyl, 1,4-dibromonaphthalene, 2,6-dibromonaphthalene and 1,2-bis(4-bromophenyl)-1,2-diphenylethene) was used to construct a class of luminescent nanoporous inorganic-organic hybrid polymers (PS-n). The structures of these polymers were confirmed by solid state ¹³C CP/MAS and ²⁹Si MAS NMR spectra, as well as Fourier transform infrared spectroscopy (FTIR). The results identify polymers with Brunauer-Emmett-Teller (BET) surface areas of up to 685 m² g^-1. The luminescence properties of these polymers were utilized for picric acid detection. Furthermore, PS-1-n (n = 6, 12, 24, 48 or 72 h) samples polymerized for different lengths of time were investigated for their energy transfer behaviour with Coumarin 6.

Original language	English
Pages (from-to)	917-924
Number of pages	8
Journal	Polymer Chemistry
Volume	6
Issue number	6
DOIs	https://doi.org/10.1039/c4py01284d
Publication status	Published - 14 Feb 2015
Externally published	Yes

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title = "Octavinylsilsesquioxane-based luminescent nanoporous inorganic-organic hybrid polymers constructed by the Heck coupling reaction",

abstract = "The Heck coupling reaction of vinyl-terminated double four-ring siloxane cages (octavinylsilsesquioxane) with aromatic bromide monomers (4,4′-dibromobiphenyl, 1,4-dibromonaphthalene, 2,6-dibromonaphthalene and 1,2-bis(4-bromophenyl)-1,2-diphenylethene) was used to construct a class of luminescent nanoporous inorganic-organic hybrid polymers (PS-n). The structures of these polymers were confirmed by solid state 13C CP/MAS and 29Si MAS NMR spectra, as well as Fourier transform infrared spectroscopy (FTIR). The results identify polymers with Brunauer-Emmett-Teller (BET) surface areas of up to 685 m2 g-1. The luminescence properties of these polymers were utilized for picric acid detection. Furthermore, PS-1-n (n = 6, 12, 24, 48 or 72 h) samples polymerized for different lengths of time were investigated for their energy transfer behaviour with Coumarin 6.",

author = "Libo Sun and Zhiqiang Liang and Jihong Yu",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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doi = "10.1039/c4py01284d",

language = "English",

volume = "6",

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journal = "Polymer Chemistry",

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T1 - Octavinylsilsesquioxane-based luminescent nanoporous inorganic-organic hybrid polymers constructed by the Heck coupling reaction

AU - Sun, Libo

AU - Liang, Zhiqiang

AU - Yu, Jihong

PY - 2015/2/14

Y1 - 2015/2/14

N2 - The Heck coupling reaction of vinyl-terminated double four-ring siloxane cages (octavinylsilsesquioxane) with aromatic bromide monomers (4,4′-dibromobiphenyl, 1,4-dibromonaphthalene, 2,6-dibromonaphthalene and 1,2-bis(4-bromophenyl)-1,2-diphenylethene) was used to construct a class of luminescent nanoporous inorganic-organic hybrid polymers (PS-n). The structures of these polymers were confirmed by solid state 13C CP/MAS and 29Si MAS NMR spectra, as well as Fourier transform infrared spectroscopy (FTIR). The results identify polymers with Brunauer-Emmett-Teller (BET) surface areas of up to 685 m2 g-1. The luminescence properties of these polymers were utilized for picric acid detection. Furthermore, PS-1-n (n = 6, 12, 24, 48 or 72 h) samples polymerized for different lengths of time were investigated for their energy transfer behaviour with Coumarin 6.

AB - The Heck coupling reaction of vinyl-terminated double four-ring siloxane cages (octavinylsilsesquioxane) with aromatic bromide monomers (4,4′-dibromobiphenyl, 1,4-dibromonaphthalene, 2,6-dibromonaphthalene and 1,2-bis(4-bromophenyl)-1,2-diphenylethene) was used to construct a class of luminescent nanoporous inorganic-organic hybrid polymers (PS-n). The structures of these polymers were confirmed by solid state 13C CP/MAS and 29Si MAS NMR spectra, as well as Fourier transform infrared spectroscopy (FTIR). The results identify polymers with Brunauer-Emmett-Teller (BET) surface areas of up to 685 m2 g-1. The luminescence properties of these polymers were utilized for picric acid detection. Furthermore, PS-1-n (n = 6, 12, 24, 48 or 72 h) samples polymerized for different lengths of time were investigated for their energy transfer behaviour with Coumarin 6.

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JO - Polymer Chemistry

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ER -

Octavinylsilsesquioxane-based luminescent nanoporous inorganic-organic hybrid polymers constructed by the Heck coupling reaction

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