Nonlinear Optical and Optical Limiting Properties of MAPbBr3/Polymethyl Methacrylate Organic Glasses

Bingkun Chen; Qianwen Zhang; Xiong Shen; Dayu Huang; Chenggang Yuan; Yuting Wang; Qiuyun Ouyang; Xuan Fang; Xue Chen

doi:10.1021/acs.jpcc.2c00163

Nonlinear Optical and Optical Limiting Properties of MAPbBr₃/Polymethyl Methacrylate Organic Glasses

Bingkun Chen, Qianwen Zhang, Xiong Shen, Dayu Huang, Chenggang Yuan, Yuting Wang, Qiuyun Ouyang^*, Xuan Fang^*, Xue Chen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The MAPbBr₃perovskite was synthesized, and X-ray diffraction proves that the MAPbBr₃perovskite is a single crystal. MAPbBr₃/polymethyl methacrylate (PMMA) organic glasses were fabricated. The MAPbBr₃single crystal shows strong UV-visible absorption and weak transmittance. Compared with the MAPbBr₃single crystal, MAPbBr₃/PMMA organic glasses show suitable UV-visible absorption and transmittance and enhanced UV-visible absorption stability. The nonlinear optical measurement of MAPbBr₃/PMMA was performed. An obviously reverse saturable absorption is observed. The nonlinear absorption coefficient is as high as 3.8 m/GW. This large nonlinear absorption coefficient is competitive compared with that of perovskite materials. Besides, the nonlinear absorption stability of MAPbBr₃/PMMA is also studied. Both the UV-visible absorption and nonlinear absorption over time prove the excellent stability of MAPbBr₃/PMMA. The superior nonlinear refraction property of MAPbBr₃/PMMA is also performed. The excellent reverse saturable absorption property and the nonlinear refraction property of MAPbBr₃/PMMA result in superior optical limiting characteristics. This work implied that MAPbBr₃/PMMA may be applied for future optical limiting devices.

Original language	English
Pages (from-to)	5743-5750
Number of pages	8
Journal	Journal of Physical Chemistry C
Volume	126
Issue number	12
DOIs	https://doi.org/10.1021/acs.jpcc.2c00163
Publication status	Published - 31 Mar 2022
Externally published	Yes

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title = "Nonlinear Optical and Optical Limiting Properties of MAPbBr3/Polymethyl Methacrylate Organic Glasses",

abstract = "The MAPbBr3perovskite was synthesized, and X-ray diffraction proves that the MAPbBr3perovskite is a single crystal. MAPbBr3/polymethyl methacrylate (PMMA) organic glasses were fabricated. The MAPbBr3single crystal shows strong UV-visible absorption and weak transmittance. Compared with the MAPbBr3single crystal, MAPbBr3/PMMA organic glasses show suitable UV-visible absorption and transmittance and enhanced UV-visible absorption stability. The nonlinear optical measurement of MAPbBr3/PMMA was performed. An obviously reverse saturable absorption is observed. The nonlinear absorption coefficient is as high as 3.8 m/GW. This large nonlinear absorption coefficient is competitive compared with that of perovskite materials. Besides, the nonlinear absorption stability of MAPbBr3/PMMA is also studied. Both the UV-visible absorption and nonlinear absorption over time prove the excellent stability of MAPbBr3/PMMA. The superior nonlinear refraction property of MAPbBr3/PMMA is also performed. The excellent reverse saturable absorption property and the nonlinear refraction property of MAPbBr3/PMMA result in superior optical limiting characteristics. This work implied that MAPbBr3/PMMA may be applied for future optical limiting devices.",

author = "Bingkun Chen and Qianwen Zhang and Xiong Shen and Dayu Huang and Chenggang Yuan and Yuting Wang and Qiuyun Ouyang and Xuan Fang and Xue Chen",

year = "2022",

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doi = "10.1021/acs.jpcc.2c00163",

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T1 - Nonlinear Optical and Optical Limiting Properties of MAPbBr3/Polymethyl Methacrylate Organic Glasses

AU - Chen, Bingkun

AU - Zhang, Qianwen

AU - Shen, Xiong

AU - Huang, Dayu

AU - Yuan, Chenggang

AU - Wang, Yuting

AU - Ouyang, Qiuyun

AU - Fang, Xuan

AU - Chen, Xue

PY - 2022/3/31

Y1 - 2022/3/31

N2 - The MAPbBr3perovskite was synthesized, and X-ray diffraction proves that the MAPbBr3perovskite is a single crystal. MAPbBr3/polymethyl methacrylate (PMMA) organic glasses were fabricated. The MAPbBr3single crystal shows strong UV-visible absorption and weak transmittance. Compared with the MAPbBr3single crystal, MAPbBr3/PMMA organic glasses show suitable UV-visible absorption and transmittance and enhanced UV-visible absorption stability. The nonlinear optical measurement of MAPbBr3/PMMA was performed. An obviously reverse saturable absorption is observed. The nonlinear absorption coefficient is as high as 3.8 m/GW. This large nonlinear absorption coefficient is competitive compared with that of perovskite materials. Besides, the nonlinear absorption stability of MAPbBr3/PMMA is also studied. Both the UV-visible absorption and nonlinear absorption over time prove the excellent stability of MAPbBr3/PMMA. The superior nonlinear refraction property of MAPbBr3/PMMA is also performed. The excellent reverse saturable absorption property and the nonlinear refraction property of MAPbBr3/PMMA result in superior optical limiting characteristics. This work implied that MAPbBr3/PMMA may be applied for future optical limiting devices.

AB - The MAPbBr3perovskite was synthesized, and X-ray diffraction proves that the MAPbBr3perovskite is a single crystal. MAPbBr3/polymethyl methacrylate (PMMA) organic glasses were fabricated. The MAPbBr3single crystal shows strong UV-visible absorption and weak transmittance. Compared with the MAPbBr3single crystal, MAPbBr3/PMMA organic glasses show suitable UV-visible absorption and transmittance and enhanced UV-visible absorption stability. The nonlinear optical measurement of MAPbBr3/PMMA was performed. An obviously reverse saturable absorption is observed. The nonlinear absorption coefficient is as high as 3.8 m/GW. This large nonlinear absorption coefficient is competitive compared with that of perovskite materials. Besides, the nonlinear absorption stability of MAPbBr3/PMMA is also studied. Both the UV-visible absorption and nonlinear absorption over time prove the excellent stability of MAPbBr3/PMMA. The superior nonlinear refraction property of MAPbBr3/PMMA is also performed. The excellent reverse saturable absorption property and the nonlinear refraction property of MAPbBr3/PMMA result in superior optical limiting characteristics. This work implied that MAPbBr3/PMMA may be applied for future optical limiting devices.

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DO - 10.1021/acs.jpcc.2c00163

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JO - Journal of Physical Chemistry C

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ER -

Nonlinear Optical and Optical Limiting Properties of MAPbBr₃/Polymethyl Methacrylate Organic Glasses

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