Nitrogen-rich energetic dianionic salts of 3, 4-bis(1H-5-tetrazolyl)furoxan with excellent thermal stability

Haifeng Huang; Zhiming Zhou; Lixuan Liang; Jinhong Song; Kai Wang; Dan Cao; Chengming Bian; Wenwen Sun; Min Xue

doi:10.1002/zaac.201100470

Nitrogen-rich energetic dianionic salts of 3, 4-bis(1H-5-tetrazolyl)furoxan with excellent thermal stability

Haifeng Huang, Zhiming Zhou^*, Lixuan Liang, Jinhong Song, Kai Wang, Dan Cao, Chengming Bian, Wenwen Sun, Min Xue

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

Nitrogen-rich 3, 4-bis(1H-tetrazol-5-yl)furoxan (H ₂BTF, 2) and its energetic salts with excellent thermal stability were successfully synthesized and fully characterized by ¹H, and ¹³C NMR, and IR spectroscopy, differential scanning calorimetry (DSC), and elemental analyses. Additionally, the structures of barium (3) and 1-methyl-3, 4, 5-triamino-triazolium (10) salts were confirmed by single-crystal X-ray diffraction. The densities of the energetic salts paired with organic cations range between 1.56 and 1.85 g·cm ^-3 as measured by a gas pycnometer. Based on the measured densities and calculated heats of formation, the detonation pressures and velocities are calculated to be in the range 23.4-32.0 GPa and 7939-8915 m·s ^-1, which make them competitive energetic materials.

Original language	English
Pages (from-to)	392-400
Number of pages	9
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	638
Issue number	2
DOIs	https://doi.org/10.1002/zaac.201100470
Publication status	Published - Feb 2012

Keywords

Density functional calculations
Detonation performance
Energetic salts
Furoxan
Tetrazoles

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title = "Nitrogen-rich energetic dianionic salts of 3, 4-bis(1H-5-tetrazolyl)furoxan with excellent thermal stability",

abstract = "Nitrogen-rich 3, 4-bis(1H-tetrazol-5-yl)furoxan (H 2BTF, 2) and its energetic salts with excellent thermal stability were successfully synthesized and fully characterized by 1H, and 13C NMR, and IR spectroscopy, differential scanning calorimetry (DSC), and elemental analyses. Additionally, the structures of barium (3) and 1-methyl-3, 4, 5-triamino-triazolium (10) salts were confirmed by single-crystal X-ray diffraction. The densities of the energetic salts paired with organic cations range between 1.56 and 1.85 g·cm -3 as measured by a gas pycnometer. Based on the measured densities and calculated heats of formation, the detonation pressures and velocities are calculated to be in the range 23.4-32.0 GPa and 7939-8915 m·s -1, which make them competitive energetic materials.",

keywords = "Density functional calculations, Detonation performance, Energetic salts, Furoxan, Tetrazoles",

author = "Haifeng Huang and Zhiming Zhou and Lixuan Liang and Jinhong Song and Kai Wang and Dan Cao and Chengming Bian and Wenwen Sun and Min Xue",

year = "2012",

month = feb,

doi = "10.1002/zaac.201100470",

language = "English",

volume = "638",

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T1 - Nitrogen-rich energetic dianionic salts of 3, 4-bis(1H-5-tetrazolyl)furoxan with excellent thermal stability

AU - Huang, Haifeng

AU - Zhou, Zhiming

AU - Liang, Lixuan

AU - Song, Jinhong

AU - Wang, Kai

AU - Cao, Dan

AU - Bian, Chengming

AU - Sun, Wenwen

AU - Xue, Min

PY - 2012/2

Y1 - 2012/2

N2 - Nitrogen-rich 3, 4-bis(1H-tetrazol-5-yl)furoxan (H 2BTF, 2) and its energetic salts with excellent thermal stability were successfully synthesized and fully characterized by 1H, and 13C NMR, and IR spectroscopy, differential scanning calorimetry (DSC), and elemental analyses. Additionally, the structures of barium (3) and 1-methyl-3, 4, 5-triamino-triazolium (10) salts were confirmed by single-crystal X-ray diffraction. The densities of the energetic salts paired with organic cations range between 1.56 and 1.85 g·cm -3 as measured by a gas pycnometer. Based on the measured densities and calculated heats of formation, the detonation pressures and velocities are calculated to be in the range 23.4-32.0 GPa and 7939-8915 m·s -1, which make them competitive energetic materials.

AB - Nitrogen-rich 3, 4-bis(1H-tetrazol-5-yl)furoxan (H 2BTF, 2) and its energetic salts with excellent thermal stability were successfully synthesized and fully characterized by 1H, and 13C NMR, and IR spectroscopy, differential scanning calorimetry (DSC), and elemental analyses. Additionally, the structures of barium (3) and 1-methyl-3, 4, 5-triamino-triazolium (10) salts were confirmed by single-crystal X-ray diffraction. The densities of the energetic salts paired with organic cations range between 1.56 and 1.85 g·cm -3 as measured by a gas pycnometer. Based on the measured densities and calculated heats of formation, the detonation pressures and velocities are calculated to be in the range 23.4-32.0 GPa and 7939-8915 m·s -1, which make them competitive energetic materials.

KW - Density functional calculations

KW - Detonation performance

KW - Energetic salts

KW - Furoxan

KW - Tetrazoles

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DO - 10.1002/zaac.201100470

M3 - Article

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SN - 0044-2313

VL - 638

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JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 2

ER -

Nitrogen-rich energetic dianionic salts of 3, 4-bis(1H-5-tetrazolyl)furoxan with excellent thermal stability

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Keywords

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