Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand

Zhongbao Jian; Dongmei Cui; Zhaomin Hou; Xiaofang Li

doi:10.1039/b926813h

Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand

Zhongbao Jian, Dongmei Cui^*, Zhaomin Hou, Xiaofang Li

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

105 Citations (Scopus)

Abstract

Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.

Original language	English
Pages (from-to)	3022-3024
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	17
DOIs	https://doi.org/10.1039/b926813h
Publication status	Published - 2010
Externally published	Yes

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title = "Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand",

abstract = "Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.",

author = "Zhongbao Jian and Dongmei Cui and Zhaomin Hou and Xiaofang Li",

year = "2010",

doi = "10.1039/b926813h",

language = "English",

volume = "46",

pages = "3022--3024",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

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T1 - Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand

AU - Jian, Zhongbao

AU - Cui, Dongmei

AU - Hou, Zhaomin

AU - Li, Xiaofang

PY - 2010

Y1 - 2010

N2 - Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.

AB - Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.

UR - http://www.scopus.com/inward/record.url?scp=77950958991&partnerID=8YFLogxK

U2 - 10.1039/b926813h

DO - 10.1039/b926813h

M3 - Article

AN - SCOPUS:77950958991

SN - 1359-7345

VL - 46

SP - 3022

EP - 3024

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand

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