Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents

Chunlin He; Joseph P. Hooper; Jean'Ne M. Shreeve

doi:10.1021/acs.inorgchem.6b02195

Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents

Chunlin He, Joseph P. Hooper, Jean'Ne M. Shreeve^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO₃^-) or periodate (IO₄^-) anions were synthesized. The synthesis of analogous I₃O₈^- salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, ¹H nuclear magnetic resonance, and ¹³C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.

Original language	English
Pages (from-to)	12844-12850
Number of pages	7
Journal	Inorganic Chemistry
Volume	55
Issue number	24
DOIs	https://doi.org/10.1021/acs.inorgchem.6b02195
Publication status	Published - 19 Dec 2016
Externally published	Yes

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title = "Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents",

abstract = "Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3-) or periodate (IO4-) anions were synthesized. The synthesis of analogous I3O8- salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, 1H nuclear magnetic resonance, and 13C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.",

author = "Chunlin He and Hooper, {Joseph P.} and Shreeve, {Jean'Ne M.}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

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AU - He, Chunlin

AU - Hooper, Joseph P.

AU - Shreeve, Jean'Ne M.

PY - 2016/12/19

Y1 - 2016/12/19

N2 - Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3-) or periodate (IO4-) anions were synthesized. The synthesis of analogous I3O8- salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, 1H nuclear magnetic resonance, and 13C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.

AB - Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3-) or periodate (IO4-) anions were synthesized. The synthesis of analogous I3O8- salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, 1H nuclear magnetic resonance, and 13C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.

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JO - Inorganic Chemistry

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ER -

Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents

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