Indium-catalysed multicomponent reaction of acetals with dibenzylamine and alkynes

Xue Lin Zhang; Qin Pei Wu; Qing Shan Zhang

doi:10.3184/174751913X13816565482472

Indium-catalysed multicomponent reaction of acetals with dibenzylamine and alkynes

Xue Lin Zhang, Qin Pei Wu^*, Qing Shan Zhang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A reaction of acetals with dibenzylamine and alkynes to form propargylamines has been developed via the activation of both C(sp3)-O and C(sp)-H bonds by InCl3. The iminium ion has been found to be the key intermediate.

Original language	English
Pages (from-to)	697-700
Number of pages	4
Journal	Journal of Chemical Research
Volume	37
Issue number	11
DOIs	https://doi.org/10.3184/174751913X13816565482472
Publication status	Published - Nov 2013

Keywords

Acetals
Alkynes
Dibenzylamine
Multicomponent reaction

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10.3184/174751913X13816565482472

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title = "Indium-catalysed multicomponent reaction of acetals with dibenzylamine and alkynes",

abstract = "A reaction of acetals with dibenzylamine and alkynes to form propargylamines has been developed via the activation of both C(sp3)-O and C(sp)-H bonds by InCl3. The iminium ion has been found to be the key intermediate.",

keywords = "Acetals, Alkynes, Dibenzylamine, Multicomponent reaction",

author = "Zhang, {Xue Lin} and Wu, {Qin Pei} and Zhang, {Qing Shan}",

year = "2013",

month = nov,

doi = "10.3184/174751913X13816565482472",

language = "English",

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pages = "697--700",

journal = "Journal of Chemical Research",

issn = "1747-5198",

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AU - Zhang, Xue Lin

AU - Wu, Qin Pei

AU - Zhang, Qing Shan

PY - 2013/11

Y1 - 2013/11

N2 - A reaction of acetals with dibenzylamine and alkynes to form propargylamines has been developed via the activation of both C(sp3)-O and C(sp)-H bonds by InCl3. The iminium ion has been found to be the key intermediate.

AB - A reaction of acetals with dibenzylamine and alkynes to form propargylamines has been developed via the activation of both C(sp3)-O and C(sp)-H bonds by InCl3. The iminium ion has been found to be the key intermediate.

KW - Acetals

KW - Alkynes

KW - Dibenzylamine

KW - Multicomponent reaction

UR - http://www.scopus.com/inward/record.url?scp=84891720230&partnerID=8YFLogxK

U2 - 10.3184/174751913X13816565482472

DO - 10.3184/174751913X13816565482472

M3 - Article

AN - SCOPUS:84891720230

SN - 1747-5198

VL - 37

SP - 697

EP - 700

JO - Journal of Chemical Research

JF - Journal of Chemical Research

IS - 11

ER -

Indium-catalysed multicomponent reaction of acetals with dibenzylamine and alkynes

Abstract

Keywords

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