Hydrothermal syntheses and crystal structures of two rectangular grid coordination polymers based on unique prismatic [M8(ip)8(4,4′-bipy)8] building blocks [M = Ni(II) or Cd(II), ip = isophthalate, bipy = bipyridine]

Jun Tao; Xiao Ming Chen; Rong Bin Huang; Lan Sun Zheng

doi:10.1016/S0022-4596(02)00053-1

Hydrothermal syntheses and crystal structures of two rectangular grid coordination polymers based on unique prismatic [M₈(ip)₈(4,4′-bipy)₈] building blocks [M = Ni(II) or Cd(II), ip = isophthalate, bipy = bipyridine]

Jun Tao, Xiao Ming Chen^*, Rong Bin Huang, Lan Sun Zheng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

Two new coordination polymers formulated as [Ni(ip)(4,4′-bipy)] (1) and [Cd(ip)(4,4′-bipy)]H₂O (2) have been hydrothermally prepared and structurally characterized. They crystallize in the triclinic space group P1̄ with Z=2 for 1 and monoclinic space group P2/c with Z=4 for 2, respectively. The dinuclear [M₂L₄(carboxylate)₄] units in each complex are bridged by V-shaped ip and linear 4,4′-bipy spacers to form unique prismatic [M₈(ip)₈(4,4′-bipy)₈] building blocks, which are further inter-connected through the mixed organic ligands to generate two-dimensional rectangular grids. The packing modes of the two two-dimensional grids are slightly different in the orientations of the ip aromatic rings with respect to the planes of the rectangular grid coordination polymers.

Original language	English
Pages (from-to)	130-134
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	170
Issue number	1
DOIs	https://doi.org/10.1016/S0022-4596(02)00053-1
Publication status	Published - Jan 2003
Externally published	Yes

Keywords

Cadmium
Coordination polymer
Crystal structure
Hydrothermal syntheses
Nickel

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Tao, J., Chen, X. M., Huang, R. B., & Zheng, L. S. (2003). Hydrothermal syntheses and crystal structures of two rectangular grid coordination polymers based on unique prismatic [M₈(ip)₈(4,4′-bipy)₈] building blocks [M = Ni(II) or Cd(II), ip = isophthalate, bipy = bipyridine]. Journal of Solid State Chemistry, 170(1), 130-134. https://doi.org/10.1016/S0022-4596(02)00053-1

@article{0e3ed79182c744d1bb1d317b16025986,

title = "Hydrothermal syntheses and crystal structures of two rectangular grid coordination polymers based on unique prismatic [M8(ip)8(4,4′-bipy)8] building blocks [M = Ni(II) or Cd(II), ip = isophthalate, bipy = bipyridine]",

abstract = "Two new coordination polymers formulated as [Ni(ip)(4,4′-bipy)] (1) and [Cd(ip)(4,4′-bipy)]H2O (2) have been hydrothermally prepared and structurally characterized. They crystallize in the triclinic space group P{\=1} with Z=2 for 1 and monoclinic space group P2/c with Z=4 for 2, respectively. The dinuclear [M2L4(carboxylate)4] units in each complex are bridged by V-shaped ip and linear 4,4′-bipy spacers to form unique prismatic [M8(ip)8(4,4′-bipy)8] building blocks, which are further inter-connected through the mixed organic ligands to generate two-dimensional rectangular grids. The packing modes of the two two-dimensional grids are slightly different in the orientations of the ip aromatic rings with respect to the planes of the rectangular grid coordination polymers.",

keywords = "Cadmium, Coordination polymer, Crystal structure, Hydrothermal syntheses, Nickel",

author = "Jun Tao and Chen, {Xiao Ming} and Huang, {Rong Bin} and Zheng, {Lan Sun}",

year = "2003",

month = jan,

doi = "10.1016/S0022-4596(02)00053-1",

language = "English",

volume = "170",

pages = "130--134",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "1",

}

Tao, J, Chen, XM, Huang, RB & Zheng, LS 2003, 'Hydrothermal syntheses and crystal structures of two rectangular grid coordination polymers based on unique prismatic [M₈(ip)₈(4,4′-bipy)₈] building blocks [M = Ni(II) or Cd(II), ip = isophthalate, bipy = bipyridine]', Journal of Solid State Chemistry, vol. 170, no. 1, pp. 130-134. https://doi.org/10.1016/S0022-4596(02)00053-1

Hydrothermal syntheses and crystal structures of two rectangular grid coordination polymers based on unique prismatic [M₈(ip)₈(4,4′-bipy)₈] building blocks [M = Ni(II) or Cd(II), ip = isophthalate, bipy = bipyridine]. / Tao, Jun; Chen, Xiao Ming; Huang, Rong Bin et al.
In: Journal of Solid State Chemistry, Vol. 170, No. 1, 01.2003, p. 130-134.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrothermal syntheses and crystal structures of two rectangular grid coordination polymers based on unique prismatic [M8(ip)8(4,4′-bipy)8] building blocks [M = Ni(II) or Cd(II), ip = isophthalate, bipy = bipyridine]

AU - Tao, Jun

AU - Chen, Xiao Ming

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

PY - 2003/1

Y1 - 2003/1

N2 - Two new coordination polymers formulated as [Ni(ip)(4,4′-bipy)] (1) and [Cd(ip)(4,4′-bipy)]H2O (2) have been hydrothermally prepared and structurally characterized. They crystallize in the triclinic space group P1̄ with Z=2 for 1 and monoclinic space group P2/c with Z=4 for 2, respectively. The dinuclear [M2L4(carboxylate)4] units in each complex are bridged by V-shaped ip and linear 4,4′-bipy spacers to form unique prismatic [M8(ip)8(4,4′-bipy)8] building blocks, which are further inter-connected through the mixed organic ligands to generate two-dimensional rectangular grids. The packing modes of the two two-dimensional grids are slightly different in the orientations of the ip aromatic rings with respect to the planes of the rectangular grid coordination polymers.

AB - Two new coordination polymers formulated as [Ni(ip)(4,4′-bipy)] (1) and [Cd(ip)(4,4′-bipy)]H2O (2) have been hydrothermally prepared and structurally characterized. They crystallize in the triclinic space group P1̄ with Z=2 for 1 and monoclinic space group P2/c with Z=4 for 2, respectively. The dinuclear [M2L4(carboxylate)4] units in each complex are bridged by V-shaped ip and linear 4,4′-bipy spacers to form unique prismatic [M8(ip)8(4,4′-bipy)8] building blocks, which are further inter-connected through the mixed organic ligands to generate two-dimensional rectangular grids. The packing modes of the two two-dimensional grids are slightly different in the orientations of the ip aromatic rings with respect to the planes of the rectangular grid coordination polymers.

KW - Cadmium

KW - Coordination polymer

KW - Crystal structure

KW - Hydrothermal syntheses

KW - Nickel

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DO - 10.1016/S0022-4596(02)00053-1

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SN - 0022-4596

VL - 170

SP - 130

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JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

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ER -