[H2dab][GaB5O10]: an Acentric Galloborate with a 4-Connected Uninodal Framework

Wenfang Liu; Chongan Chen; Guoyu Yang

doi:10.1007/s40242-024-4130-5

[H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework

Wenfang Liu, Chongan Chen, Guoyu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A new acentric galloborate (GBO) [H₂dab][GaB₅O₁₀] (1, 1,4-dab: 1,4-diaminobutane) has been synthesized under solvothermal conditions. The alternation of 4,4-connected GaO₄ and B₅O₁₀ cluster build up the 3D [GaB₅O₁₀]_n²ⁿ⁻ uninodal framework, which contains three pairs of helical channels with 8-member ring (MR) and 7-MR apertures, respectively. Compound 1 exhibits a moderate second harmonic generation (SHG) response of 1.8 times that of KH₂PO₄ (KDP), indicating its potential application in UV regions. The acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs’ family. (Figure presented.)

Original language	English
Pages (from-to)	747-752
Number of pages	6
Journal	Chemical Research in Chinese Universities
Volume	40
Issue number	4
DOIs	https://doi.org/10.1007/s40242-024-4130-5
Publication status	Published - Aug 2024

Keywords

Galloborate
Nonlinear optics
Solvothermal synthesis
Zeolitic framework

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10.1007/s40242-024-4130-5

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title = "[H2dab][GaB5O10]: an Acentric Galloborate with a 4-Connected Uninodal Framework",

abstract = "A new acentric galloborate (GBO) [H2dab][GaB5O10] (1, 1,4-dab: 1,4-diaminobutane) has been synthesized under solvothermal conditions. The alternation of 4,4-connected GaO4 and B5O10 cluster build up the 3D [GaB5O10]n2n− uninodal framework, which contains three pairs of helical channels with 8-member ring (MR) and 7-MR apertures, respectively. Compound 1 exhibits a moderate second harmonic generation (SHG) response of 1.8 times that of KH2PO4 (KDP), indicating its potential application in UV regions. The acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs{\textquoteright} family. (Figure presented.)",

keywords = "Galloborate, Nonlinear optics, Solvothermal synthesis, Zeolitic framework",

author = "Wenfang Liu and Chongan Chen and Guoyu Yang",

note = "Publisher Copyright: {\textcopyright} Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2024.",

year = "2024",

month = aug,

doi = "10.1007/s40242-024-4130-5",

language = "English",

volume = "40",

pages = "747--752",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

publisher = "Springer International Publishing AG",

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TY - JOUR

T1 - [H2dab][GaB5O10]

T2 - an Acentric Galloborate with a 4-Connected Uninodal Framework

AU - Liu, Wenfang

AU - Chen, Chongan

AU - Yang, Guoyu

N1 - Publisher Copyright: © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2024.

PY - 2024/8

Y1 - 2024/8

N2 - A new acentric galloborate (GBO) [H2dab][GaB5O10] (1, 1,4-dab: 1,4-diaminobutane) has been synthesized under solvothermal conditions. The alternation of 4,4-connected GaO4 and B5O10 cluster build up the 3D [GaB5O10]n2n− uninodal framework, which contains three pairs of helical channels with 8-member ring (MR) and 7-MR apertures, respectively. Compound 1 exhibits a moderate second harmonic generation (SHG) response of 1.8 times that of KH2PO4 (KDP), indicating its potential application in UV regions. The acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs’ family. (Figure presented.)

AB - A new acentric galloborate (GBO) [H2dab][GaB5O10] (1, 1,4-dab: 1,4-diaminobutane) has been synthesized under solvothermal conditions. The alternation of 4,4-connected GaO4 and B5O10 cluster build up the 3D [GaB5O10]n2n− uninodal framework, which contains three pairs of helical channels with 8-member ring (MR) and 7-MR apertures, respectively. Compound 1 exhibits a moderate second harmonic generation (SHG) response of 1.8 times that of KH2PO4 (KDP), indicating its potential application in UV regions. The acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs’ family. (Figure presented.)

KW - Galloborate

KW - Nonlinear optics

KW - Solvothermal synthesis

KW - Zeolitic framework

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U2 - 10.1007/s40242-024-4130-5

DO - 10.1007/s40242-024-4130-5

M3 - Article

AN - SCOPUS:85198344995

SN - 1005-9040

VL - 40

SP - 747

EP - 752

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 4

ER -

[H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework

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