Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks

Gang Zhao; Chunlin He; Dheeraj Kumar; Joseph P. Hooper; Gregory H. Imler; Damon A. Parrish; Jean'ne M. Shreeve

doi:10.1016/j.cej.2019.02.192

Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks

Gang Zhao, Chunlin He, Dheeraj Kumar, Joseph P. Hooper, Gregory H. Imler, Damon A. Parrish, Jean'ne M. Shreeve^*

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

In order to deal with biological weapons effectively, agent defeat weapons (ADWs) have been developed to destroy or neutralize the active agents in the resulting plume by releasing large amounts of strong biocides upon detonation. Based on the strategy of coupling of an energetic building block and a biocidal building block, several functional energetic materials were synthesized and fully characterized. All of the compounds have high densities (2.50–2.94 g/cm³), and high iodine contents (57.96 and 76.32%), making them good candidates as biocidal agents. Compounds 4 and 9 exhibit good detonation performances (4: D_v = 3679 m s⁻¹; P = 8.07 GPa and 9: D_v = 4044 m s⁻¹; P = 8.70 GPa) (CHEETAH 7) and their high iodine content suggests their promise as energetic biocides.

Original language	English
Pages (from-to)	244-251
Number of pages	8
Journal	Chemical Engineering Journal
Volume	368
DOIs	https://doi.org/10.1016/j.cej.2019.02.192
Publication status	Published - 15 Jul 2019

Keywords

Biocidal materials
Biocidal polyiodo building blocks
Coupling
Energetic building blocks
Energetic materials

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10.1016/j.cej.2019.02.192

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title = "Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks",

abstract = "In order to deal with biological weapons effectively, agent defeat weapons (ADWs) have been developed to destroy or neutralize the active agents in the resulting plume by releasing large amounts of strong biocides upon detonation. Based on the strategy of coupling of an energetic building block and a biocidal building block, several functional energetic materials were synthesized and fully characterized. All of the compounds have high densities (2.50–2.94 g/cm3), and high iodine contents (57.96 and 76.32%), making them good candidates as biocidal agents. Compounds 4 and 9 exhibit good detonation performances (4: Dv = 3679 m s−1; P = 8.07 GPa and 9: Dv = 4044 m s−1; P = 8.70 GPa) (CHEETAH 7) and their high iodine content suggests their promise as energetic biocides.",

keywords = "Biocidal materials, Biocidal polyiodo building blocks, Coupling, Energetic building blocks, Energetic materials",

author = "Gang Zhao and Chunlin He and Dheeraj Kumar and Hooper, {Joseph P.} and Imler, {Gregory H.} and Parrish, {Damon A.} and Shreeve, {Jean'ne M.}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = jul,

day = "15",

doi = "10.1016/j.cej.2019.02.192",

language = "English",

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T1 - Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks

AU - Zhao, Gang

AU - He, Chunlin

AU - Kumar, Dheeraj

AU - Hooper, Joseph P.

AU - Imler, Gregory H.

AU - Parrish, Damon A.

AU - Shreeve, Jean'ne M.

PY - 2019/7/15

Y1 - 2019/7/15

N2 - In order to deal with biological weapons effectively, agent defeat weapons (ADWs) have been developed to destroy or neutralize the active agents in the resulting plume by releasing large amounts of strong biocides upon detonation. Based on the strategy of coupling of an energetic building block and a biocidal building block, several functional energetic materials were synthesized and fully characterized. All of the compounds have high densities (2.50–2.94 g/cm3), and high iodine contents (57.96 and 76.32%), making them good candidates as biocidal agents. Compounds 4 and 9 exhibit good detonation performances (4: Dv = 3679 m s−1; P = 8.07 GPa and 9: Dv = 4044 m s−1; P = 8.70 GPa) (CHEETAH 7) and their high iodine content suggests their promise as energetic biocides.

AB - In order to deal with biological weapons effectively, agent defeat weapons (ADWs) have been developed to destroy or neutralize the active agents in the resulting plume by releasing large amounts of strong biocides upon detonation. Based on the strategy of coupling of an energetic building block and a biocidal building block, several functional energetic materials were synthesized and fully characterized. All of the compounds have high densities (2.50–2.94 g/cm3), and high iodine contents (57.96 and 76.32%), making them good candidates as biocidal agents. Compounds 4 and 9 exhibit good detonation performances (4: Dv = 3679 m s−1; P = 8.07 GPa and 9: Dv = 4044 m s−1; P = 8.70 GPa) (CHEETAH 7) and their high iodine content suggests their promise as energetic biocides.

KW - Biocidal materials

KW - Biocidal polyiodo building blocks

KW - Coupling

KW - Energetic building blocks

KW - Energetic materials

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DO - 10.1016/j.cej.2019.02.192

M3 - Article

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SN - 1385-8947

VL - 368

SP - 244

EP - 251

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

ER -

Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks

Abstract

Keywords

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