Effect dehydrants to increasing molecular weight of condensed polylactic acid

Meng Yan Yin, Rong Jie Yang, Ding Hua Li

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Citation (Scopus)

Abstract

The polylactic acid (PLA) was prepared by direct melt polycondensation using lactic acid aqueous solution as raw material. Considering of the difficulty to rule out small molecules of water, magnesium or magnesium methoxide which could react with water were used as dehydrant and added in the PLA polycondensation, respectively. The determination of moisture, GPC and DSC results showed that both the magnesium and magnesium methoxide are effective in dehydration, the molecular weight of final products PLA is significantly improved and the latter is better. Both of them have a good promoting effect on polycondensation reaction to get a higher molecular weight polylactic acid products. For the time of adding magnesium and magnesium methoxide, it is better to add in the late stage of polycondensation reaction rather than early stage. Furthermore, magnesium has a smaller influence on crystallization of PLA, whereas the crystallinity of PLA is greatly reduced after adding magnesium methoxide.

Original languageEnglish
Title of host publicationResearch in Mechanical Engineering and Material Science
PublisherTrans Tech Publications Ltd.
Pages525-528
Number of pages4
ISBN (Print)9783037859285
DOIs
Publication statusPublished - 2014
Event2013 International Conference on Mechanical, Material Engineering, MME 2013 - Shiyan, Hubei, China
Duration: 23 Nov 201324 Nov 2013

Publication series

NameApplied Mechanics and Materials
Volume456
ISSN (Print)1660-9336
ISSN (Electronic)1662-7482

Conference

Conference2013 International Conference on Mechanical, Material Engineering, MME 2013
Country/TerritoryChina
CityShiyan, Hubei
Period23/11/1324/11/13

Keywords

  • Dehydrant
  • Direct melt polycondensation
  • Magnesium
  • Magnesium methoxide
  • Polylactic acid

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